Scientific Journals
list of publication (pdf)
2023
Fixative effect of 2-oxo-2-phenylacetates in fine fragrance and eau-de-toilette applications
D. L. Berthier, J. Girard, K. M. Fromm, A. Herrmann. Flavour Fragr J. 2023; 00: 1-10. doi:10.1002/ffj.3769
Photophysical Properties of Anthracene Derivatives
A. Kastrati, F. Oswald, A. Scalabre, K. M. Fromm. photochem 2023, 3(2), 227-273. DOI: 10.3390/photochem3020015
Stimuli-Responsive and Antibacterial Cellulose-Chitosan Hydrogels Containing Polydiacetylene Nanosheets
E. S. Madivoli, J. V. Schwarte, P. G. Kareru, A. N. Gachanja, K. M. Fromm. Polymers 2023, 15(5), 1062. DOI: 10.3390/polym15051062
Chances and challenges of long-distance electron transfer for cellular redox reactions
B. Giese, M. Karamash, K. M. Fromm. FEBS Letters 2023, 597, 166-173. DOI: 10.1002/1873-3468.14493
2022
Reduction Kinetic of Water Soluble Metal Salts by Geobacter sulfurreducens: Fe2+/Hemes Stabilize and Regulate Electron Flux Rates
M. Karamash, M. Stumpe, J. Dengjel, C. A. Salgueiro, B. Giese, K. M. Fromm. Frontiers in microbiology 2022, 13, 909109. doi.org/10.3389/fmicb.2022.909109
A Rapid, Highly Sensitive and Selective Phosgene Sensor Based on 5,6-Pinenepyridine
A. B. Solea, C. Curty, K. M. Fromm, C. Allemann, O. Mamula Steiner; Chemistry an European Journal 2022, 19, 4, 1310-1322. DOI: 10.1002/chem.202201772
Isolation of Cellulose Nanofibers from Oryza sativa Residues via TEMPO Mediated Oxidation
E. S. Madivoli, P. G Kareru, A. N. Gachanta, S. M. Mugo, D. M. Sujee, K. M. Fromm; Journal of Natural Fibers 2022, ASAP. DOI: 10.1080/15440478.2020.1764454
Complexation Behavior of Pinene–Bipyridine Ligands towards Lanthanides: The Influence of the Carboxylic Arm
A. B. Solea, L. Yang, A. Crochet, K. M. Fromm, C. Allemann, O. Mamula; Chemistry 2022, 4, 1, 18-30. DOI:10.3390/chemistry4010002 Special Issue to Celebrate the Life and Work of Alexander von Zelewsky (1936–2021)
Multifunctional Anthracene-Based Ni-MOF with Encapsulated Fullerenes: Polarized Fluorescence Emission and Selective Separation of C70 from C60
S. I. Vasylevskyi, G. Raffy, S. Salentinig, A. Del Guerzo, C. E. Housecroft, K. M. Fromm, D. M. Bassani ACS Appl. Mater. Interfaces 2022, 14,1. DOI: 10.1021/acsami.1c19141
2021
Memorial Issue Dedicated to Dr. Howard D. Flack: The Man behind the Flack Parameter
C. E. Housecroft, K. M. Fromm, Chemistry 2021, 3, 3, 818-820. DOI: 10.3390/chemistry3030058
Efficient synthesis of isoindolones by intramolecular cyclisation of pyridinylbenzoic acids
A. B. Solea, S. Wang, X.-S. Xue, A. Crochet, K. M. Fromm, K. N. Houk, O. Mamula, C. Allemann; Org. Biomol. Chem. 2021, 19, 8025-8029. DOI: 10.1039/D1OB01343B
NMR reveals the interplay between SilE and SilB model peptides in the context of silver resistance
L. Babel, M.-H. Nguyen, C. Mittelheisser, M. Martin, K. M. Fromm, O. Walker, M. Hologne; Chem. Comm. 2021, 57, 8726-8729. (cover) DOI: 10.1039/D1CC02597J
7-OH quinoline Schiff bases: are they the long awaited tautomeric bistable switches ?
A. Georgiev, D. Yordanov, N. Ivanova, V. Deneva, N. Vassilev, F. Kamounah, M. Pittelkow, A. Crochet, K. M. Fromm, L. Antonov; Dyes and Pigment 2021, 195, 109739. DOI:10.1016/j.dyepig.2021.109739
General Chemistry: Large Classes, Mixed Public, Three Languages (A Personal Experience)
K. M. Fromm; Chimia 2021, 75, 39-44. doi:10.2533/chimia.2021.39
On the Ni0.75Ti1.5Fe0.5(PO4)3/C NASICON-type electrode material
M. Srout, M. Amou, K. M. Fromm, I. Saadoune; J. Electroanal. Chem. 2021, 880, 114913. DOI: 10.1016/j.jelechem.2020.114913
2020
New Antimicrobial Strategies Based on Metal Complexes
M. Claudel, J. V. Schwarte, K. M. Fromm; Chemistry 2020, 2(4), 849-899. DOI: 10.3390/chemistry2040056
Handling (Nano)Silver as Antimicrobial Agent: Therapeutic Window, Dissolution Dynamics, Detection Methods and Molecular Interactions
S.-L. Abram, K. M. Fromm; Chem. Eur. J. 2020, 26, 10948-10971. DOI: 10.1002/chem.202002143
A Simple Reaction for DNA Sensing and Chemical Delivery
E. Janett, K.-L. Diep, K. M. Fromm, C. G. Bochet; ACS Sens. 2020, 5, 8, 2338-2343. DOI: 10.1021/acssensors.0c00988
Bimetallic Salen-based compounds and their potential applications
A. Finelli, S.-L. Abram, N. Hérault, A. Crochet, K. M. Fromm; Cryst. Growth Des. 2020, 20,8, 4945-4958. DOI: 10.1021/acs.cgd.9b01610
Isolation of cellulose nanofibers from oryza sativa residues via TEMPO mediated oxidation
E. S. Madivoli, P. G. Kareru, A. N. Gachanja, S. M. Mugo, D. M. Sujee & K. M. Fromm; J. Nat. Fibers 2020. DOI: 10.1080/15440478.2020.1764454
OH group effect in the stator of β-diketone based rotary switches
S. Hristova, F. S. Kamounah, A. Crochet, N. Vassilev, K. M. Fromm, L. Antonov; Chemistry 2020, 2(2), 374-389. (Cover) DOI: 10.3390/chemistry2020024
Indirect solvent assisted tautomerism in 4-substituted phthalimide 2-hydroxy-Schiff bases
D. Yordanov, V. Deneva, A. Georgiev, A. Crochet, K. M. Fromm, L. Antonov; Spectroc. Acta A 2020, 118416. DOI: 10.1016/j.saa.2020.118416
A nano-rattle SnO2@carbon composite anode material for high-energy Li-ion batteries by melt diffusion impregnation
S. Maharajan, N. H. Kwon, P. Brodard, K. M. Fromm; Nanomaterials 2020, 10(4). DOI: 10.3390/nano10040804
Improvement of the electrochemical performance by partial chemical substitution into the lithium site of titanium phosphate-based electrode materials for lithium-ion batteries: LiNi0.25Ti1.5 Fe0.5(PO4)3
M. Srout, M. El Kazzi, H. Ben Youcef, N. Semlal, K. M. Fromm, I. Saadoune; J. Power Sources 2020, 228114. DOI: 10.1016/j.jpowsour.2020.228114
Li0.5Ni0.5Ti1.5Fe0.5(PO4)3/C electrode material for lithium ion batteries exhibiting faster kinetics and enhanced stability
M. Srout, N. H. Kwon, H. Ben Youcef, N. Semlal, K. M. Fromm, I. Saadoune; ACS Appl. Mater. Interfaces 2020, 12, 16, 18496-18503. DOI: 10.1021/acsami.0c00712
Appropriate Buffers for Studying the Bioinorganic Chemistry of Silver(I)
L. Babel, S. Bonnet-Gomez, K. M. Fromm; Chemistry 2020, 2, 193-202. DOI: 10.3390/chemistry2010012
Metal Nanoparticle-Microbe Interactions: Synthesis and Antimicrobial Effects
M. R. Khan, K. M. Fromm, T. F. Rizvi, B. Giese, F. Ahamad, R. J. Turner, M. Füeg, E. Marsili, Part. Part. Syst. Charact. 2020, 1900419. DOI: 10.1002/ppsc.201900419
Silver-Containing Titanium Dioxide Nanocapsules for Combating Multidrug-Resistant Bacteria
N. Hérault, J. Wagner, S.-L. Abram, J. Widmer, L. Horvath, D. Vanhecke, C. Bourquin, K. M. Fromm, Int. J. Nanomedicine. 2020; 15:1267-1281. DOI: 10.2147/IJN.S231949
Kinetics and Mechanism of Mineral Respiration: How Iron‐Hemes Synchronize Electron Transfer Rates
V. Chabert, L. Babel, M. P. Füeg, M. Karamash, E. S. Madivoli, N. Herault, J. M. Dantas, C. A. Salgueiro, B. Giese, K. M. Fromm, Angew. Chem. Int. Ed., 2020, 59, pp 12331-12336. DOI: 10.1002/anie.201914873
Angew. Chem. (German Ed.): DOI: 10.1002/ange.201914873
Tautomerism and Self-Association in the Solution of New Pinene-Bipyridine and Pinene-Phenanthroline Derivatives
A. B. Solea, I. Cornu, V. Deneva, A. Crochet, K. M. Fromm, L. Antonov, C. Allemann, O. Mamula, Molecules, 2020, 25(2), 298. DOI: 10.3390/molecules2520298
Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!
K. M. Fromm, Coord. Chem. Reviews 2020, 408, 213193. DOI: 10.1016/j.ccr.2020.213193
2019
Surface modifications of positive-electrode materials for lithium ion batteries
N. H. Kwon, J. Conder, M. Srout, K. M. Fromm, Chimia, 2019, 73, 880-893. DOI: 10.2533/chimia.2019.880
Sequential multi-target sensor: In3+, Fe2+ and Fe3+ discrimination by anthracene-based probe
A. Finelli, V. Chabert, N. Hérault, A. Crochet, C. Kim, K. M. Fromm, Inorg. Chem., 2019, 58, 20, 13796-13806. DOI: 10.1021/acs.inorgchem.9b01478
New Ni0.5Ti2(PO4)3@C Nasicon‐type electrode material with high rate capability performance for Lithium‐ion batteries: Synthesis and Electrochemical properties
I. Saadoune, M. Srout, N.-H. Kwon, L. Wen, A. Züttel, K. M. Fromm, ChemSusChem, 2019, 12, 1-9. DOI: 10.1002/cssc.201902002
Different coordination abilities of 1,7- and 4,7-phenanthroline in the reactions with copper(II) salts: structural characterization and biological evaluation of the reaction products
N. Lj. Stevanović, T. P. Andrejević, A. Crochet, T. Ilic-Tomic, N. S. Drašković, J. Nikodinovic-Runic, K. M. Fromm, Miloš I. Djuran, Biljana Đ. Glišić, Polyhedron, 2019, 173, 114112. DOI: 10.1016/j.poly.2019.114112
Tautomerism as primary signaling mechanism in metal sensing: the case of amide group
V. Deneva, G. Dobrikov, A. Crochet, D. Nedeltcheva, K. M. Fromm and L. Antonov, Belstein J. Org. Chem. , 2019, 15, 1898-1906. DOI: 10.3762/bjoc.15.185
Efficient Perovskite Nanocrystal Light-Emitting Diodes Using Benzimidazole-Substituted Anthracene Derivative as the Electron Transport Material
S. Kumar, T. Marcato, S. Vasylevskyi, J. Jagielski, K. M. Fromm and C. Shih, J. Mater. Chem. C, 2019, 7, 8938-8945. DOI: 10.1039/C9TC02352F.
Compartmentalization of Alkaline Earth Metals in Salen-type Cu- and Ni-Complexes in Solution and in the Solid State
A. Finelli, N. Hérault, A. Crochet, K. M. Fromm, ACS Omega 2019, 4, 6, 10231-10242. DOI: 10.1021/acsomega.9b00365
Anion-induced structural diversity of Zn and Cd coordination polymers based on bis-9,10-(pyridine-4-yl)-anthracene, their luminescent properties and highly efficient sensing of nitro derivatives and herbicides
S. I. Vasylevskyi, D. M. Bassani, K. M. Fromm, Inorganic Chemistry 2019, 58, 9, 5646-5653. DOI: 10.1021/acs.inorgchem.8b03628
Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection
A. Pavic, N. D. Savić, B. Đ. Glišić, A. Crochet, S. Vojnovic, A. Kurutos, D. Stanković, K. M. Fromm, J. Nikodinovic-Runic, M. Djuran, Journal of Inorganic Biochemistry 2019, 195, 149-163. DOI: 10.1016/j.jinorgbio.2019.03.017
Synthesis and structural analysis of polynuclear silver(I) complexes with 4,7-phenanthroline
I. Stanojević, N. D. Savić, A. Crochet, K. M. Fromm, M. I. Djuran, B. Đ. Glišić, Journal of Serbian Chemical Society 2019, 84, 689-699 . DOI: 10.2298/JSC190226024S
Isomerization and aggregation of 2-(2-(2-hydroxy-4-nitrophenyl)hydrazono)-1-phenylbutane1,3-dione: recent evidences from theory and experiment
S. Hristova, F. S. Kamounah, A. Crochet, P. E. Hansen, K. M. Fromm, D. Nedeltcheva, L. Antonov, Journal of Molecular Liquids 2019, 283, 242-248. DOI: 10.1016/j.molliq.2019.03.073
Synthesis and Applications of Nanocontainers and Nanorattles
S.-L. Abram, P. Yep, K. M. Fromm, Chimia 2019, 73, 12-16. DOI: 10.2533/chimia.2019.12
Functional Polymers Through Mechanochemistry
S. Schrettl, D. W. R. Balkenende, C. Calvino, M. Karman, A. Lavrenova, L. N. Neumann, Y. Sagara, E. Verde-Sesto, M. di Giannantonio, Y. C. Simon, K. M. Fromm, M. Lattuada, C. Weder, Chimia 2019, 73, 7-11. DOI: 10.2533/chimia.2019.7
Tautomerism in azo dyes: Border cases of azo and hydrazo tautomers as possible NMR reference compounds
V. Deneva; S. Hristova; L. Antonov; A. Lyčka; A. Crochet; K. M. Fromm , Dyes and pigments 2019, 165, 157-163. DOI: 10.1016/j.dyepig.2019.02.015
2018
Metallocene as Mechanophore in Polymers Leads to Metal Ion Release & Oxidation (Highlight)
M. Di Giannantonio, M. A. Ayer, E. Verde-Sesto, M. Lattuada, C. Weder, K. M. Fromm, Chimia 2018, 72, 12, 902. DOI: 10.2533/chimia.2018.902
Betti Bases from 4-(3-Pyridazo)-1-naphthol: Synthesis, Coordination Behaviour and Unusual Substitution Reactions
V. B. Kurteva, L. A. Lubenov, B. L. Shivachev, R. P. Nikolova, K. M. Fromm, ChemistrySelect 2018, 3, 12017–12021. DOI: 10.1002/slct.201802745
Polyaspartamide Functionalized Catechol-Based Hydrogels Embedded with Silver Nanoparticles for Antimicrobial Properties
M. Tan, Y. Choi, J. Kim, J.-H. Kim, K. M. Fromm, Polymers 2018, 10, 1188-1203. DOI: 10.3390/polym10111188
Solid-state structure and antimicrobial and cytotoxicity studies of a cucurbit[6]uril-like Cu6L4 constructed from 3,5-bis[(1H-tetrazol-5-yl)methyl]-4H-1,2,4-triazol-4-amine
S. I. Vasylevskyi, A. Holzheu, K. M. Fromm, Acta Cryst. C 2018, C74, 1413-1419. DOI: 10.1107/S2053229618013670
Mononuclear silver(I) complexes with 1,7-phenanthroline as potent inhibitors of Candida growth
N. D. Savić, S. Vojnovic, B. Đ.Glišić, A. Crochet, A. Pavic, G. V. Janjić, M. Pekmezović, I. M. Opsenica, K. M. Fromm, J, Nikodinovic-Runic, M. I. Djuran, European Journal of Medicinal Chemistry 2018, 156, 760-773. DOI: 10.1016/j.ejmech.2018.07.049
Alpha-helical folding of SilE models upon Ag(His)(Met) motif formation
V. Chabert, M. Hologne, O. Sénèque, O. Walker, K. M. Fromm, Chem. Comm. 2018, 54, 10419-10422. DOI: 10.1039/c8cc03784a
With inside cover
Trithiocarbonate-Functionalized PNiPAAm-Based Nanocomposites for Antimicrobial Properties
M. Tan, L. Horvàth, P. S. Brunetto and K. M. Fromm, Polymers 2018, 10(6), 665-690. DOI: 10.3390/polym10060665
Triggered metal ion release and oxidation: Ferrocene as new mechanophore in polymers
M. Di Giannantonio, M. A. Ayer, E. Verde-Sesto, M. Lattuada, C. Weder, K. M. Fromm, Angew. Chem., Int. Ed. 2018, online. DOI: 10.1002/anie.201803524
also available in German in Angew. Chem. 2018, online. DOI: 10.1002/ange.201803524
Early stage sustainability evaluation of new, nanoscale cathode materials for Li-ion batteries
R. Hischier, N.-H. Kwon, J.-P. Brog, K. M. Fromm, ChemSusChem 2018, 11, 13, 2068-2076. DOI: 10.1002/cssc.201800109
Amide Neighbouring-Group Effects in Peptides: Phenylalanine as Relay Amino Acid in Long-Distance Electron Transfer
J. G. Nathanael, L. F. Gamon, M. Cordes, P. R. Rablen,T. Bally, K. M. Fromm, B. Giese, U. Wille, ChemBioChem, 2018, 19, 922-926. DOI:10.1002/cbic.201800098
A Concept for stimulated proton transfer in 1-(phenyldiazenyl)naphtalen-2ols
S. Hristova, V. Deneva, M. Pittelkow, A. Crochet, F. S. Kamounah, K. M. Fromm, P. E. Hansen, L. Antonov, Dyes and Pigments 2018, 156, 91-99. DOI: 10.1016/j.dyepig.2018.03.070
Versatile synthesis of chiral 6-oxoverdazyl radical ligands – new building blocks for multifunctional molecule-based magnets
A. B. Solea, T. Wohlhauser, P. Abbasi, Y. Mongbanziama, A. Crochet, K. M. Fromm, G. Novitchi, C. Train, M. Pilkington, O. Mamula, Dalton Trans. 2018, 47, 4785-4789. DOI: 10.1039/C8DT00840J
Ag Nanoencapsulation for Antimicrobial Applications
S.-L. Abram, J. Gagnon, M. Priebe, N. Hérault, K. M. Fromm, Chimia 2018, 72, 249-253. cover. DOI: 10.2533/chimia.2018.249
Puckering behavior in six new phosphoric triamides containing aliphatic six- and seven-membered ring groups and a database survey of analogous ring-containing structuresB. V. Alviri, M. Pourayoubi, A. Saneei, M. Keikha, A. van der Lee. A. Crochet, A. Ajees, M. Nečas, K. M. Fromm, K. Damodaran, T. A. Jenny, Tetrahedron 2018, 74, 1, 28-41. DOI: 10.1016/j.tet.2017.11.030
Threading Salen-type Cu- and Ni-Complexes into One-Dimensional Coordination Polymers: Solution versus Solid State and the Size Effect of the Alkali Metal Ion
A. Finelli, N. Hérault, A. Crochet, K. M. Fromm, Cryst. Growth Des. 2018, 2, 1215-1226. DOI: 10.1021/acs.cgd.7b01769
WRI1 and DGAT1 regulate tocochromanol metabolism in arabidopsis
S. Pellaud, A. Bory, V. Chabert, J. Romanens, L. Chaisse-Leal, A. V. Doan, L. Frey, A. Gust, K. M. Fromm, L. Mène-Saffrané, New Phytologist 2018, 217, 245–260. DOI: 10.1111/nph.14856
Cis- and Trans-9,10-di(1H-imidazol-1-yl)-anthracene based coordination polymers of ZnII and CdII: synthesis, crystal structures and luminescence properties
S. I. Vasylevskyi, K. Regeta, A. Ruggi, S. Petoud, C. Piguet, and K. M. Fromm, Dalton Trans., 2018, 47, 596-607. DOI: 10.1039/C7DT03758A
The synergistic cooperation of NH⋯O and CH⋯O hydrogen bonds in the structures of three new phosphoric triamides
A. Saneei, M. Pourayoubi, J. P. Jasinski, T. A. Jenny, A. Crochet, K. M. Fromm & A. C. Keeley, Phosphorus, Sulfur, and Silicon and the Related Elements, 2018, 193, 257-266 . DOI: 10.1080/10426507.2017.1399128
A Review: Carbon Additives in LiMnPO4- and LiCoO2-Based Cathode Composites for Lithium Ion Batteries
N.-H Kwon, D. Mouck-Makanda, K. M. Fromm, Batteries 2018, 4, 50-73. DOI: 10.3390/batteries4040050
2017
Characteristics and properties of nano-LiCoO2 synthesized by pre-organized single source precursors: Li-ion diffusivity, electrochemistry and biological assessment
J.-P. Brog, A. Crochet, J. Seydoux, M. J. D. Clift, B. Baichette, S. Maharajan, H. Barosova, P. Brodard, M. Spodaryk, A. Züttel, B. Rothen-Rutishauser, N.-H. Kwon, K. M. Fromm, JNanobiotechnol 2017, 15, 58. DOI: 10.1186/s12951-017-0292-3
Influence of the Sacrificial Polystyrene Removal Pathway on the TiO2 Nanocapsule Structure
N. Herault, K. M. Fromm, Helvetica Chimica Acta 2017, 100(6), e1700014 . DOI: 10.1002/hlca.201700014
Different molecular assemblies in two new phosphoric triamides with the same C(O)NHP(O)(NH)2 skeleton: crystallographic study and Hirshfeld surface analysis
A. Saneei, M. Pourayoubi, T. A. Jenny, A. Crochet, K. M. Fromm, E. S. Shchegravina, Chemical papers 2017, 17, 1809. DOI: 10.1007/s11696-017-0168-x
Influence of anions and solvent molecules on the packing and emission spectra of coordination polymers based on silver ions and an anthracene derivative
J. Chen, N. Voutier, J. Rajabi, A. Crochet, D. M. Bassani, K. M. Fromm, CrysEngComm 2017, 19, 5106-5113. DOI: 10.1039/C7CE00846E
Model peptide studies of Ag+ binding sites from the silver resistance protein SilE
V. Chabert, M. Hologne, O. Sénèque, A. Crochet, O. Walker, K. M. Fromm, Chem. Commun. 2017, 53, 6105–6108. DOI: 10.1039/c7cc02630g
Quantitative Nano-characterization of Polymers Using Atomic Force Microscopy
M. Radiom, S. Kozhuharov, P. Kong, M. di Giannantonio,M. Ayer, P. Maroni, A. F. M. Kilbinger, K. M. Fromm, C. Weder, M. Borkovec, Chimia 2017, 71(4), 195-198. DOI: 10.2533/chimia.2017.195
Formation of silver nanoparticles by electron transfer in peptides and c-cytochromes
S. I. Vasylevskyi, S. Kracht, P. Corcosa, K. M. Fromm, B. Giese, M. Füeg, Angew. Chem. Int. Ed. 2017, 56, 5926 –5930. DOI: 10.1002/anie.201702621
Heptacoordinate Co(II) complex: a new architecture for photochemical hydrogen production
F. Lucarini, M. Pastore, S. I. Vasylevskyi, M. Varisco, E. Solari, A. Crochet, K. M. Fromm, F. Zobi, A. Ruggi, Chem. Eur. J. 2017, 23, 6768-6771, DOI: 10.1002/chem.201701427
Embedding CeO2 nanocontainers in a TiO2 coating on glass surfaces
J. Gagnon, R. A. Caruso, and K. M. Fromm, AIMS Bioengineering 2017, 4(1), 171-178. DOI: 10.3934/bioeng.2017.1.171
Antimicrobial silver-filled silica nanorattles with low immunotoxicity in dendritic cells
M. Priebe, J. Widmer, N. Suhartha Löwa, S.-L. Abram, I. Mottas, A.-K. Woischnig, P. S. Brunetto, N. Khanna, C. Bourquin, K. M. Fromm, Nanomedicine: NBM 2017, 13(1), 11-22. DOI: 10.1016/j.nano.2016.08.002
Nanoparticle shapes of LiMnPO4, Li+-diffusion orientation and diffusion coefficients for high volumetric energy Li+-ion cathodes
N.-H. Kwon, H. Yin, T. Vavrova, J. H.-W. Lim, U. Steiner, B. Grobéty, K. M. Fromm, J. Power Sources 2017, 342, 231-240. DOI: 10.1016/j.jpowsour.2016.11.111
2016
Going nano for batteries and drug delivery
S.-L. Abram, J.-P. Brog, P. S. Brunetto, A. Crochet, J. Gagnon, N.-H. Kwon, S. Maharajan, M. Priebe, K. M. Fromm, Chimia 2016, 70(9), 661. DOI:10.2533/chimia.2016.661
Tandem ring-opening-ring-closing metathesis for functional metathesis catalysts
A. A. Nagarkar, M. Yasir, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Angew. Chem., Int. Ed. 2016, 55, 12343-12346. DOI: 10.1002/anie.201604112
Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-ol
S. Chetioui, D.-A. Rouag, J.-P. Djukic, C. G. Bochet, R. Touzani, C. Bailly, A. Crochet and K. M. Fromm, Acta Cryst. 2016, 72(8), 1093-1098. DOI:10.1107/S205698901601080X
Synthesis of new polyether ether ketone derivatives with silver binding site and coordination compounds of their monomers with different silver salts
J. Girard, N. Joset, A. Crochet, M. Tan, A. Holzheu, P. S. Brunetto, K. M. Fromm, Polymers 2016, 8(6), 208. DOI:10.3390/polym8060208
Synthesis, characterization, antibacterial activity and cytotoxicity of hollow TiO2-coated CeO2 nanocontainers encapsulating silver nanoparticles for controlled silver release
Mixed metal multinuclear Cr(III) cage compounds and coordination polymers based on unsubstituted phenolate: design, synthesis, mechanism and properties
A. Crochet, J.-P. Brog, K. M. Fromm, Cryst. Growth Des. 2016, 16(1), 189-199. DOI: 10.1021/acs.cgd.5b01084
A thermo- and mechanoresponsive cyano-substituted oligo(p-phenylene vinylene) derivative with five emissive states
Y. Sagara, A. Lavrenova, A. Crochet, Y. C. Simon, K. M. Fromm, C. Weder, Chem. Eur. J. 2016, 22(13), 4374–4378. DOI: 10.1002/chem.201600272
Preventing implant-associated infections by silver coating
R. Kuehl, P. S. Brunetto, A.-K. Woischnig, M. Varisco, Z. Rajacic, J. Vosbeck, L. Terracciano, K. M. Fromm, N. Khanna, Antimicrob. Agents Chemother. 2016, 60(4), 2467-2475. DOI: 10.1128/AAC.02934-15
The first phosphoramide–mercury(II) complex with a Cl2 Hg–OP[N(C)(C)]3 segment
A. Saneei, M. Pourayoubi, A. Crochet, K. M. Fromm, Acta Crystallogr. C. Struct. Chem. 2016, 72(3), 230-233. DOI: 10.1107/S2053229616002394
2015
Synthesis, X-ray structure and DFT calculation of oxido-vanadium(V) complex with a tridentate Schiff base ligand
I. Sheikhshoaie, S. Y. Ebrahimipour, A. Crochet, K. M. Fromm, Res. Chem. Intermed. 2015, 41(4), 1881-1891. DOI 10.1007/s11164-013-1317-7
Nanorattles or yolk-shell nanoparticles-What are they, How are they made, and What are they good for?
M. Priebe, K. M. Fromm, Chem. Eur. J. 2015, 21(10), 3854-3874. DOI:10.1002/chem.201405285
Electron transfer in peptides: on the formation of silver nanoparticles
S. Kracht, M. Messerer, M. Lang, S. Eckhardt, M. Lauz, B. Grobety, K. M. Fromm, B. Giese, Angew. Chem. Int. Ed. 2015, 54(10), 2912-2916. DOI: 10.1002/anie.201410618
Controlled tautomeric switching in azonaphthols tuned by substituents on the phenyl ring
L. Antonov, , , , , , , , , ChemPhysChem, 2015, 16(3), 649-657. DOI: 10.1002/cphc.201402691
cis-Dioxido-molybdenum(VI) complexes of tridentate ONO hydrazone Schiff base: synthesis, characterization, X-ray crystal structure, DFT calculation and catalytic activity
S. Y. Ebrahimipour, H. Khabazadeh, J. Castro, I. Sheikhshoaie, A. Crochet, K. M. Fromm, Inorg. Chem. Acta 2015, 427, 52-61. Doi:10.1016/j.ica.2014.11.023
4-Hydroxy-1-naphthaldehydes: proton transfer or deprotonation
Y. Manolova, V. Kurteva, L. Antonov, H. Marciniak, S. Lochbrunner, A. Crochet, K. M. Fromm, F. S. Kamounah, P. E. Hansen, Phys. Chem. Chem. Phys. 2015, 17(15), 10238-10249. DOI: 10.1039/C5CP00870K
Toxicity and protective effects of cerium oxide nanoparticles (nanoceria) depending on their preparation method, particle size, cell type, and exposure route
J. Gagnon, K. M. Fromm, Eur. J. Inorg. Chem. 2015, 27, 4510-4517. DOI: 10.1002/ejic.201500643
Towards cardiolite-inspired carbon monoxide releasing molecules – reactivity of d4, d5 rhenium and d6 manganese carbonyl complexes with isocyanide ligands
E. Kottelat, V. Chabert, A. Crochet, K. M. Fromm, F. Zobi, Eur. J. Inorg. Chem. 2015, 34, 5628-5638. DOI: 10.1002/ejic.201500756
Layer-by-layer grown scalable redox-active ruthenium-based molecular multilayer thin films for electrochemical applications and beyond
V. Kaliginedi, H. Ozawa, A. Kuzume, S. Maharajan, I. V. Pobelov, N.-H. Kwon, M. Mohos, P. Broekmann, K. M. Fromm, M.-A. Haga, T. Wandlowski, Nanoscale 2015, 7(42), 17685–17692. DOI: 10.1039/c5nr04087f
Nanomaterials meet Li-ion batteries
N.-H. Kwon, J.-P. Brog, S. Maharajan, A. Crochet, K. M. Fromm, Chimia 2015, 69(12), 734-736. DOI: 10.2533/chimia.2015.734
Construction of polynuclear lanthanide (Ln = DyIII, TbIII, and NdIII) cage complexes using pyridine–pyrazole-based ligands: versatile molecular topologies and SMM behavior
S. Bala, M. S. Bishwas, B. Pramanik, S. Khanra, K. M. Fromm, P. Poddar, R. Mondal, Inorg. Chem. 2015, 54 (17), 8197–8206. DOI: 10.1021/acs.inorgchem.5b00334
Integrating silver compounds and nanoparticles into ceria nanocontainers for antimicrobial applications
J. Gagnon, M. J. D. Clift, D. Vanhecke, D. A. Kuhn, P. Weber, A. Petri-Fink, B. Rothen-Rutishauser, K. M. Fromm, J. Mat. Chem. B 2015, 3(9), 1760-1768. DOI: 10.1039/C4TB02079K
2014
Investigation on the growth and characterization of novel creatinium malate single crystal
S. Mathuri, M. Kayalvizhi, G. Vasuki, R. Ramesh Babu, K. Ramamurthi, A. Crochet, K. M. Fromm, Chem. Sci. Rev. Lett. 2014, 3(12), 1208-1218. ISSN 2278-6783
One-pot synthesis and catalytic properties of encapsulated silver nanoparticles in silica nanocontainers
M. Priebe, K. M. Fromm, Particles and Particle Systems Characterization 2014, 31(6), 645-651. DOI: 10.1002/ppsc.201300304
New antimicrobial and biocompatible implant coating with synergic silver–vancomycin conjugate action
M. Varisco, N. Khanna, P. S. Brunetto, K. M. Fromm, ChemMedChem. 2014,9(6), 1221-1230. DOI: 10.1002/cmdc.201400072
Impact of composite structure and morphology on electronic and ionic conductivity of carbon contained LiCoO2 cathode
N.-H. Kwon, H. Yin, P. Brodard, C. Sugnaux, K. M. Fromm, Electrochim. Acta 2014, 134, 215-221. DOI:10.1016/j.electacta.2014.04.121
Synthesis, crystal structure and antimicrobial activities of di ((E)-2-(pyridine-2-ylmethylene)hydrazinecarboxamide) cobalt(II) dichloride trihydrate
J. Novina, G. Vasuki, M. Suresh, M. S. A. Padusha, K. M. Fromm, A. Crochet, Phys. Science Inter. J. 2014, 4, 816-824. DOI: 10.9734/PSIJ/2014/7803
A new mixed-ligand copper(II) complex of (E)-N’-(2-hydroxybenzylidene)acetohydrazide: synthesis, characterization, NLO behavior, DFT calculation and biological activities
S. Y. Ebrahimipour, I. Sheikhshoaie, A. Crochet, M. Khaleghi, K. M. Fromm, J. Mol. Struct. 2014, 1072, 267-276. DOI:10.1016/j.molstruc.2014.05.024
2013
pH-Dependent coordination of AgI ions by histidine: experiment, theory, and a model for SilE
L. Mirolo, T. Schmidt, S. Eckhardt, M. Meuwly, K. M. Fromm, Chem. Eur. J. 2013, 19(5), 1754-1761. DOI: 10.1002/chem.201201844
7-[(Morpholin-4-yl)(phenyl)methyl]quinolin-8-ol
J. J. Novina, G. Vasuki, C. Muthukumar, A. Sabastiyan, A. Crochet, K. M. Fromm, Acta Cryst. 2013, 69(1), o45. DOI:10.1107/S1600536812049343
Ethyl 5-methoxy-2-trifluoromethyl-1H-indol-3-carboxyl-ate
A. Crochet, I. Alimi, C. G. Bochet, K. M. Fromm, Acta Cryst. 2013, 69(3), o339. DOI:10.1107/S1600536813002614
Barium bright and heavy
K. M. Fromm, Nature Chem. 2013, 5(2), 146. DOI:10.1038/nchem.1551
Ring a bell: disubstituted calix[4]arene as ligand for transition metal chlorides
A. Crochet, K. M. Fromm, Polyhedron 2013, 52, 610-616. DOI:10.1016/j.poly.2012.08.004
Rings, chains and helices: new antimicrobial silver coordination compounds with (iso-)nicotinic acid derivatives
I. Chevrier, J. L. Sagué, P. S. Brunetto, N. Khanna, Z. Rajacic, K. M. Fromm, Dalton Trans. 2013, 42(1), 217-231. DOI: 10.1039/C2DT31259J
Kinetics of ion transport through supramolecular channels in single crystals
C. D. Assouma, A. Crochet, Y. Chérémond, B. Giese, K. M. Fromm, Angew. Chem. Int. Ed. 2013, 52(17), 4682-4685. DOI: 10.1002/anie.201208195
CFA-2 and CFA-3 (coordination framework Augsburg University-2 and -3); novel MOFs assembled from trinuclear Cu(I)/Ag(I) secondary building units and 3,3’,5,5’-tetraphenyl-bipyrazolate ligands
M. Grzywa, C. Gessner, D. Denysenko, B. Bredenkötter, F. Gschwind, K. M. Fromm, W. Nitek, E. Klemm, D. Volkmer, Dalton Trans. 2013, 42(19), 6909-6921. DOI: 10.1039/C3DT32302A
Development of a polystyrene sulfonate/silver nanocomposite with self-healing properties for biomaterial applications
J. Girard, P. S. Brunetto, O. Braissant, Z. Rajacic, N. Khanna, R. Landmann, A. U. Daniels, K. M. Fromm, C. R. Chim. 2013, 16(6), 550-556. DOI:10.1016/j.crci.2013.04.010
Silver coordination polymers with isonicotinic acid derived short polyethylene gylcol – Synthesis, structures, anion effect and solution behavior
K. M. Fromm, J. L. Sagué, A. Y. Robin, Inorg. Chim. Acta 2013, 403, 2-8. DOI:10.1016/j.ica.2012.12.021
A family of immobilizable chiral bis(pinenebipyridine) ligands
A. Pöllnitz, R. Skupienski, H. Stoeckli-Evans, A. Crochet, A. Silvestru, K. M. Fromm, O. Mamula, Synlett 2013, 24(19), 2555-2558. DOI: 10.1055/s-0033-1339847
Bioinorganic chemistry of silver: its interactions with amino acids and peptides
K. M. Fromm, Chimia 2013, 67(12), 851-854. DOI:10.2533/chimia.2013.851
Controlled tautomerism – switching caused by an “underground” anionic effect
L. Antonov, V. Deneva, V. Kurteva, D. Nedeltcheva, A. Crochet, K. M. Fromm, RSC Advances 2013, 3(47), 25410-25416 . DOI: 10.1039/C3RA45326J
Polymorphism, what it is and how to identify it: a systematic review
J.-P. Brog, C.-L- Chanez, A. Crochet, K. M. Fromm, RSC Advances 2013, 3(38), 16905-16931. DOI: 10.1039/C3RA41559G
Nanobio-silver: its interactions with peptides and bacteria, and its uses in medicine
S. Eckhardt, P. S. Brunetto, J. Gagnon, M. Priebe, B. Giese, K. M. Fromm, Chem. Rev.2013, 113(7), 4708-4754. DOI: 10.1021/cr300288v
Silver coordination compounds with antimicrobial properties
K. M. Fromm, Appl. Organomet. Chem. 2013, 12, 683-687. DOI: 10.1002/aoc.3047
2012
Tautomerism in 1-phenylazo-4-naphthols: experimental results vs. quantum-chemical predictions
L. Antonov, V. Kurteva, A. Crochet, L. Mirolo, K. M. Fromm, S. Angelova, Dyes and Pigments 2012, 92(1), 714-723. DOI:10.1016/j.dyepig.2011.06.026
Switching azonaphthols containing a side chain with limited flexibility. Part 1. Synthesis and tautomeric properties
V. B. Kurteva, L. M. Antonov , D. V. Nedeltcheva, A. Crochet, K. M. Fromm, R. P. Nikolova, B. L. Shivachev, M. S. Nikiforova, Dyes and Pigments 2012, 92(3), 1266-1277. DOI:10.1016/j.dyepig.2011.07.013
Synthesis and characterization of new pentacoordinate iron based aryloxide complexes
Y. Chérémond, A. Crochet, K. M. Fromm, Eur. J. Inorg. Chem. 2012, 2012(16), 2725-2730. DOI: 10.1002/ejic.201101054
Effect of increasing ligand length on the structure of silver complexes
F. Gschwind, K. M. Fromm, CrystEngComm 2012, 14(11), 4008-4015. DOI: 10.1039/C2CE25110H
A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid [Bmim][N(Tf)2]
Z.-L. Xie, H.-B. Xu, A. Gessner, M. U. Kumke, M. Priebe, K. M. Fromm, A. Taubert, J. Mat. Chem. 2012, 22(16), 8110-8116. DOI: 10.1039/C2JM15862K
Enhanced electrochemical performance of < 30 nm thin LiMnPO4 nanorods with a reduced amount of carbon as a cathode for lithium ion batteries
N. H. Kwon, K. M. Fromm, Electrochim. Acta 2012, 69, 38-44. DOI:10.1016/j.electacta.2012.02.040
Single crystal to single crystal polymorphic phase transition of a silver nitrate 24-crown-8 complex and its pseudo-polymorphism
J. Girard, K. M. Fromm, CrystEngComm 2012, 14(20), 6487-6491. DOI: 10.1039/C2CE25875G
The influence of dipole moments on the mechanism of electron transfer through helical peptides
M. Lauz, S. Eckhardt, K. M. Fromm, B. Giese, PhysChemChemPhys 2012, 14(40), 13785-13788. DOI: 10.1039/C2CP41159H
A comparative study of (poly)ether adducts of alkaline earth iodides an overview including new compounds
W. Maudez, K. M. Fromm, Z. Anorg. Allg. Chem. 2012, 638(11), 1810-1819. DOI: 10.1002/zaac.201200231
Antibacterial properties of nanoparticles
M. J. Hajipour, K. M. Fromm, A. Akbar Ashkarran, D. Jimenez de Aberasturi, I. R. de Larramendi, T. Rojo, V. Serpooshan, W. J. Parak, M. Mahmoudi, Trends Biotechnol. 2012, 30(10), 499-511. DOI:10.1016/j.tibtech.2012.06.004
Efficient amine end-functionalization of living ring-opening metathesis polymers
A. A. Nagarkar, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Macromolecules 2012, 45(11), 4447-4453. DOI: 10.1021/ma300602p
Preparation of imidazolidin-4-ones and their evaluation as hydrolytically cleavable precursors for the slow release of bioactive volatile carbonyl derivatives
A. Trachsel, B. Buchs, G. Godin, A. Crochet, K. M. Fromm, A. Herrmann, Eur. J. Org. Chem. 2012, 14, 2837-2854. DOI: 10.1002/ejoc.201200081
2011
Give silver a shine
K. M. Fromm, Nature Chemistry 2011, 3(2), 178. DOI:10.1038/nchem.970
Electron transfer in peptides: the influence of charged amino acids
J. Gao, P. Müller, M. Wang, S. Eckhardt, M. Lauz, K. M. Fromm, B. Giese, Angew. Chem., Int. Ed. 2011, 50(8), 1926-1930. DOI: 10.1002/anie.201003389
In vitro biocompatibility of new silver(I) coordination compound coated-surfaces for dental implant applications
P. S. Brunetto, T. Vig Slenters, K. M. Fromm, Materials 2011, 4, 355-367. DOI:10.3390/ma4020355
Polymorph of dibenzo-24-crown-8 and its mercury complex
A. Crochet, E. Kottelat, A. Fleury, M. Neuburger, K. M. Fromm, Z. Anorg. Allg. Chem. 2011, 637(6), 672-675. DOI: 10.1002/zaac.201100065
(E)-1-(4-Methoxyanthracen-1-yl)-2-phenyldiazene
A. Crochet, K. M. Fromm, V. Kurteva, L. Antonov, Acta Cryst E, Struct Reports Online 2011, E67(4), o993. ISSN 1600-5368
Tetraethylene glycol adducts of alkaline earth halides
F. Gschwind, K. M. Fromm, Z. Anorg. Allg. Chem. 2011, 637(12), 1871-1879. DOI: 10.1002/zaac.201100192
Coordination networks of mercury(II) halides and polyether ligand
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2011, 637(14-15), 2089-2092. DOI: 10.1002/zaac.201100283
Nanoencapsulation of anti-microbial drugs
J. Gagnon, P. Weber, K. M. Fromm, Europ. Cells & Materials 2011, 21(2), 49. ISSN 1473-2262
2010
From alkaline earth ion aggregates via transition metal coordination polymer networks towards heterometallic single source precursors for oxidic materials
F. Gschwind, A. Crochet. W. Maudez, K. M. Fromm, Chimia 2010, 64(5), 299-302. DOI: 10.2533/chimia.2010.299
Polyether adducts of d-block metal compounds as starting materials for new cluster compounds
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2010, 636(8), 1484-1496. DOI: 10.1002/zaac.201000022
Of chains and rings: synthetic strategies and theoretical investigations for tuning the structure of silver coordination compounds and their applications
T. Vig Slenters, J. L. Sagué, P. S. Brunetto, S. Zuber, A. Fleury, L. Mirolo, A. Y. Robin, M. Meuwly, O. Gordon, R. Landmann, A. U. Daniels, and K. M. Fromm, Materials 2010, 3(5), 3407-3429. DOI:10.3390/ma3053407
Tautocrowns: a concept for a sensing molecule with an active side-arm
L. M. Antonov, V. B. Kurteva, S. P. Simeonov, V. V. Deneva, A. Crochet, K. M. Fromm, Tetrahedron 2010, 66(24), 4292-4297. DOI:10.1016/j.tet.2010.04.049
Silver coordination polymers for prevention of implant infection: thiol interaction, impact on respiratory chain enzymes, and hydroxyl radical induction
O. Gordon, T. Vig. Slenters, P. S. Brunetto, A. E. Villaruz, D. E. Sturdevant, M. Otto, R. Landmann, K. M. Fromm, Antimicrob. Agents Chemother. 2010, 54(10), 4208-4218. DOI: 10.1128/AAC.01830-09
Synthesis, X-ray crystal structure, thermal and solution studies of a centrosymmetric metal-organic polymer based on proton transfer methodology
H. Eshtiagh-Hosseini, A. Hassanpoor, N. Alfi, M. Mirzaei, K. M. Fromm, A. Shokrollahi, F. Gschwind, E. Karami, J. Coord. Chem. 2010, 63(18), 3175-3186. DOI: 10.1080/00958972.2010.508518
Excimer formation in crystalline and nanostructured coordination polymers
J. Chen, A. Neels, K. M. Fromm, Chem. Commun. 2010, 46(43), 8282-8284. DOI: 10.1039/C0CC03011B
On the chemical synthesis of titanium nanoparticles from ionic liquids
A. A. Ayi, V. Khare, P. Strauch, J. Girard, K. M. Fromm, A. Taubert, Monatshefte für Chemie 2010, 141(12), 1273-1278. DOI: 10.1007/s00706-010-0403-4
A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure
H. Eshtiagh‐Hosseini, M. Mahjoobizadeh, M. Mirzaei, K. M. Fromm, A. Crochet, Eur. J. Chem. 2010, 1(3), 179-181. DOI:10.5155/eurjchem.1.3.179‐181.44
Coordination polymer networks: an alternative to classical polymers?
K. M. Fromm, J. L. Sagué, L. Mirolo, Macromol. Symp. 2010, 291–292, 75–83. DOI: 10.1002/masy.201050509
2009
Silver-nanoparticle formation in different sizes induced by peptides identified within split-and-mix libraries
K. Belser, T. Vig Slenters, C. Pfumbidzai, G. Upert, L. Mirolo, K. M. Fromm, H. Wennemers, Angew. Chem. Int. Ed. 2009, 48(20), 3661-3664. DOI: 10.1002/anie.200806265
The heterometallic clusters of trivalent rare earth metals of [Ln(OPh)6{Li(dme)}3] with Ln = Eu and Sm
W. Maudez, K. M. Fromm, Helv. Chim. Acta 2009, 92(11), 2349-2356. DOI: 10.1002/hlca.200900171
Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol
D. Nedeltcheva, F. S. Kamounah, S. Fadhil, L. Mirolo, K. M. Fromm, L. Antonov, Dyes and Pigments 2009, 83(1), 121-126. DOI:10.1016/j.dyepig.2009.04.002
Multitopic ligand design: a concept for single-source precursors
F. Gschwind, O. Sereda, K. M. Fromm, Inorg. Chem. 2009, 48(22), 10535-10547. DOI: 10.1021/ic9009064
Getting hooked on supramolecular coordination chemistry
K. M. Fromm, Chimia 2009, 63(12), 858-859. DOI:10.2533/chimia.2009.858
2008
Antimicrobial coatings for implant surfaces
P. S. Brunetto, K. M. Fromm, Chimia 2008, 62(4), 249-252. DOI:10.2533/chimia.2008.249
Silver nanoparticle engineering via oligovaline organogels
A. Mantion, A. G. Guex, A. Foelske, L. Mirolo, K. M. Fromm, M. Painsi, A. Taubert, Soft Matter 2008, 4(3), 606-617. DOI: 10.1039/B712826F
Amino acids in iron oxide mineralization: (incomplete) crystal phase selection is achieved even with single amino acids
A. Mantion, F. Gozzo, B. Schmitt, W. B. Stern, Y. Gerber, A. Y. Robin, K. M. Fromm, M. Painsi, A. Taubert, J. Phys. Chem. C 2008, 112(32), 12104-12110. DOI: 10.1021/jp075449u
Silver coordination compounds as light-stable, nano-structured and anti-bacterial coatings for dental implant and restorative materials
T. Vig Slenters, I. Hauser-Gerspach, A. U. Daniels, K. M. Fromm, J. Mat. Chem. 2008, 18(44), 5359–5362. DOI: 10.1039/B813026D
Counterion effect on the formation of coordination polymer networks between AgNO3 and L (2,2′-oxybis(ethane-2,1-diyl) diisonicotinate). Part 2
J. L. Sagué, M. Meuwly, K. M. Fromm, CrystEngComm 2008, 10(11), 1542-1549. DOI: 10.1039/B803158D
Combating implant infections. Remarks by a women’s team
C. R. Arciola, N. Balaban, L. Baldassarri, K. Fromm, G. M. Hansch, U. Obst, E. Presterl, S. Stefani, J. Verran, L. Visai, The International journal of artificial organs 2008, 31(9), 858-864. ISSN:0391-3988
Coordination polymer networks with s-block metal ions
K. M. Fromm, Coord. Chem. Rev.,2008, 252(8+9), 856-885. DOI: 10.1016/j.ccr.2007.10.032
2007
Structure–property relationships: Polymorphism, solvates, and clay behavior in the one-dimensional coordination polymer chains [Ag(L)(NO3)](H2O)n, L = ethanediyl bis(isonicotinate), n= 0, and 2
A. Y. Robin, J. L. Sague Doimeadios, A. Neels, T. Vig Slenters, K. M. Fromm, Inorg. Chim. Acta 2007, 360(1), 212-220. DOI:10.1016/j.ica.2006.07.086
Analogy of the coordination chemistry of alkaline earth metal and lanthanide Ln2+ ions: the isostructural zoo of mixed metal cages [IM(OtBu)4{Li(thf)}4(OH)] (M=Ca, Sr, Ba, Eu), [MM’6(OPh)8(thf)6] (M=Ca, Sr, Ba, Sm, Eu, M’=Li, Na), and their derivatives with 1,2-dimethoxyethane
W. Maudez, M. Meuwly, K. M. Fromm, Chem. Eur. J. 2007, 13(29), 8302 – 8316. DOI: 10.1002/chem.200700597
From simple rings to one-dimensional channels with calix[8]arenes, water clusters and alkali metal ions
R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Tetrahedron 2007, 63(44), 10751-10757. DOI:10.1016/j.tet.2007.07.048
Transport properties of solid state crown ether channel systems
K. M. Fromm, R. D. Bergougnant, Solid State Sciences 2007, 9(7), 580-587. DOI:10.1016/j.solidstatesciences.2007.04.012
2006
Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies
M. Dulak, R. Bergougnant, K. M. Fromm, H. R. Hagemann, A. Y. Robin, T. A. Wesolowski, Spectrochim. Acta Mol. Biomol. Spectrosc. 2006, 64A(2), 532–548. DOI:10.1016/j.saa.2005.07.060
[Ag(isonicotinamide)2NO3]2– a stable form of silver nitrate
T. Dorn, K. M. Fromm, C. Janiak, Aust. J. Chem. 2006, 59(1), 22-25. DOI: 10.1071/CH05270
On the coordination behaviour of NO3– in coordination compounds with Ag+. Part 1. Solubility effect on the formation of coordination polymer networks between AgNO3 and L(L = ethanediylbis(isonicotinate) as a function of solvent
A. Y. Robin, J. L. Sagué, K. M. Fromm, CrystEngComm, 2006, 8, 403-416. DOI: 10.1039/B517191A
Di-Benzo-18-crown-6 and its derivatives as ligands in the search for ion channels
K. M. Fromm, R. D. Bergougnant, A. Y. Robin, Z. Anorg. Allg. Chem. 2006, 632(5), 828-836. DOI: 10.1002/zaac.200500470
Substitution reactions on alkaline earth metal iodides: a large anionic Sr12-aggregate [{Sr6(O)(μ3-I)(I)2(OtBu)7(thf)3}2(μ-I)]–
W. Maudez, T. Vig-Slenters, L. Mirolo, A. Fleury, K. M. Fromm, Main Group Chemistry 2006, 5(1), 41-49. DOI: 10.1080/10241220600841862
Substitution reactions on CaI2: synthesis of mixed metal lithium-calcium-phenolates, and cluster transformation as a function of solvent
W. Maudez, D. Häussinger, K. M. Fromm, Z. Anorg. Allg. Chem. 2006, 632(14), 2295-2298. DOI: 10.1002/zaac.200600170
Film-forming polymers containing in the main-chain dibenzo crown ethers with aliphatic (C10-C16), aliphatic-aromatic, or oxyindole spacers
M. G. Zolotukhin, M.C. G. Hernández, A. M. Lopez, L. Fomina, G. Cedillo, A. Nogales, T. Ezquerra, D. Rueda, H. M. Colquhoun, K. M. Fromm, A. Ruiz-Treviño, M. Ree, Macromolecules 2006, 39(14), 4696-4703. DOI: 10.1021/ma052148e
The first two-dimensional polycatenane: a new type of robust network obtained by Ag-connected one-dimensional polycatenanes
J. L. Sagué, K. M. Fromm, Cryst. Growth Des. 2006, 6(7), 1566-1568. DOI: 10.1021/cg060255+
A structural study of copper(II) carboxylates: crystal structure and physical characterisation of [Cu2(2-bromopropanoato)4(caffeine)2]
F. Valach, M. Melnik, G. Bernardinelli, K. M. Fromm, J. Chem. Cryst. 2006, 36(9), 571-580. DOI: 10.1007/s10870-006-9102-8
Coordination polymer networks with O- and N-donors: what they are, why and how they are made
A. Y. Robin, K. M. Fromm, Coord. Chem. Rev. 2006, 250(15+16), 2127-2157. DOI: 10.1016/j.ccr.2006.02.013
Recent advances in tailoring the aggregation of heavier alkaline earth metal halides, alkoxides and aryloxides from non-aqueous solvents
K. M. Fromm, Dalton Transactions, 2006, 43, 5103-5112. DOI: 10.1039/B611042H
2005
Recent advances in the chemistry of “clusters” and coordination polymers of alkali, alkaline earth metal and group 11 compounds
K. M. Fromm, E. D. Gueneau, A. Y. Robin, W. Maudez, J. Sague, R. Bergougnant, Z. Anorg. Allg. Chem. 2005, 631(10), 1725-1740. DOI: 10.1002/zaac.200500079
Chiral S-1,1’-bi-2-naphthol (S-BINOL) as a synthon for supramolecular hydrogen-bonded {(S-BINOLATn-)(S-BINOL)n}-strands with naphthyl-paneled cavities or channels for a Cd(NH3)4-fragment (n = 2) or [Ag(NH3)2]+ (n = 1). Part 2.
B. Paul, C. Näther, K. M. Fromm, C. Janiak, CrystEngComm. 2005, 7(51), 309–319. DOI: 10.1039/B502202A
“Hooked on” calix[8]arenes: a (H2O)10-cluster with an unprecedented structure
R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Cryst. Growth Des. 2005, 5(5), 1691-1694. DOI: 10.1021/cg050201k
Concomitant crystallization of two polymorphs – a ring and a helix: concentration effect on supramolecular polymorphism or isomerism
K. M. Fromm, J. L. Sagué Doimeadios, A. Y. Robin, Chem. Commun. 2005, 36, 4548-4550. DOI: 10.1039/B506389B
2004
∞1[M(μ-O2C-C6H4-CO2)(NH3)2] (M = Cu, Cd; O2C-C6H4-CO2 = benzene-1,4-dicarboxylate, terephthalate): 1D coordination polymers with strong inter-chain hydrogen bonding
B. Paul, B. Zimmermann, K. M. Fromm, C. Janiak, Z. Anorg. Allg. Chem. 2004, 630(11), 1650-1654. DOI: 10.1002/zaac.200400240
Molecular paneling of rac-1,1’-bi-2-naphthol/~ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4or 6]2+complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2-(BINOL)2}-strands
B. Paul, C. Näther, B. Walfort, K. M. Fromm, B. Zimmermann, H. Lang, C. Janiak, CrystEngComm 2004, 6(51), 293-297. DOI: 10.1039/B410933C
How many structures are there for {[AgL](NO3)(H2O)n}? Water-content dependent variations in the structure of {[AgL](NO3)(H2O)n}, n = 0, 1, 2; L = ethanediyl bis(isonicotinate)
A. Y. Robin, M. Meuwly, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 2004, 6(60), 336–343. DOI: 10.1039/B413232G
Structures of alkali and alkaline earth metal clusters with oxygen donor ligands
K. M. Fromm, E. D. Gueneau, Polyhedron2004, 23(9), 1479-1504. DOI : 10.1016/j.poly.2004.04.014
2003
Synthesis and structural analysis of the polymetallated alkali calixarenes [M4(p-tert-butylcalix[4]arene-4H)(thf)x]2·n THF (M = Li, K; n = 1 or 6; x = 4 or 5) and [Li2(p-tert-butylcalix[4]arene-2H)(H2O)(μ-H2O)(thf)]·3THF
E. D. Gueneau, K. M. Fromm, H. Goesmann, Chem. Eur. J. 2003, 9(2), 509-514. DOI: 10.1002/chem.200390053
“One-dimensional water” and “one-dimensional acid”: synthesis and the unique crystal structure of [(H2O)⊂(DB18C6)(μ2-H2O)2/2][(H3O)⊂(DB18C6)(μ2-H2O)2/2]I3 (DB18C6 = dibenzo-18-crown-6)
K. M. Fromm, E. D. Gueneau, H. Goesmann, C. G. Bochet, Z. Anorg. Allg. Chem. 2003, 629(4), 597-600. DOI: 10.1002/zaac.200390101
Understanding the formation of new clusters of alkali and alkaline earth metals: a new synthetic approach, single crystal structures and theoretical calculations
K. M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, H. Chermette, J. Am. Chem. Soc. 2003, 125(12), 3593-3604. DOI: 10.1021/ja0205737
Oxygen donor stabilized alkaline earth metal iodides
K M. Fromm, Chimia 2003, 57(4), 175-178. CODEN:CHIMAD; ISSN:0009-4293
Polar molecular precursors for alkali and alkaline earth metal clusters and low-dimensional polymer structures: the solid state structures of [CaI(dme)3]I, and cis-[SrI2(diglyme)2] (dme = CH3OC2H4OCH3; diglyme = CH3(OC2H4)2OCH3)
K. M. Fromm, W. Maudez, Eur. J. Inorg. Chem. 2003, 18, 3440-3444. DOI: 10.1002/ejic.200300241
Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)
A. Y. Robin, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 2003, 5(71), 405–410. DOI: 10.1039/B309410C
Coordination compounds
K. M. Fromm, Kirk-Othmer Encyclopedia of Chemical Technology, Copyright © 2003 by John Wiley & Sons, Inc. DOI: 10.1002/0471238961.0315151801180308.a01.pub2
2002
Crown ethers as stabilizing ligands for asymmetric coordination: synthesis, crystal structure, and physical properties of [Na ⊂ (DB18C6)I(thf)], [Na ⊂ (DB18C6)I(1,3-dioxolane)], and [Na ⊂ (DB24C8)]I (DB18C6 = Dibenzo-18-crown-6, DB24C8 = Dibenzo-24-crown-8)
K. M. Fromm, E. D. Gueneau, J.-P. Rivera, G. Bernardinelli, H. Goesmann, Z. Anorg. Allg. Chem. 2002, 628(1), 171-178. DOI: 10.1002/1521-3749(200201)628:1<171::AID-ZAAC171>3.0.CO;2-K
Ionic or covalent? Can some first hints be derived from the solid state structures of alkaline earth metal halide adducts?
K. M. Fromm, CrystEngComm. 2002, 4(57), 318-322. DOI: 10.1039/B201975M
Recent advances in the chemistry of clusters and inorganic polymers of alkali and alkaline earth metal compounds
K. M. Fromm, Chimia 2002, 56(12), 676-680. CODEN:CHIMAD; ISSN:0009-4293
Electron transfer through bridging molecular structures
M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Ann. N. Y. Acad. Sci. 2002, 960, 16-28. DOI: 10.1111/j.1749-6632.2002.tb03022.x
2001
Electron transfer through molecular bridges between reducible pentakis(thiophenyl)benzene subunits
M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Chem. Eur. J. 2001, 7(6), 1266-1272. DOI: 10.1002/1521-3765(20010316)7:6<1266::AID-CHEM1266>3.0.CO;2-S
Hydrogen-bonding and metal-ion mediated self-assembly of a nanoporous crystal lattice
D. G. Kurth, K. M. Fromm, J.-M. Lehn, Eur. J. Inorg. Chem. 2001, (6), 1523-1526. DOI: 10.1002/1099-0682(200106)2001:6<1523::AID-EJIC1523>3.0.CO;2-2
A logical concept of structure prediction derived from supramolecular polymers of alkaline earth metal halides formed by hydrogen bonding and complexation of the metal ion
K. M. Fromm, Chem. Eur. J. 2001, 7(10), 2236-2244. DOI: 10.1002/1521-3765(20010518)7:10<2236::AID-CHEM2236>3.0.CO;2-S
Synthesis and crystal structure of the one-dimensional polymer compound 1∞{[Ba(OTf)2(thf)3]2[Ba(OTf)2(thf)2]}(OTf = CF3SO3–) – excerpts from a three-dimensional structure as an access to new materials?
K. M. Fromm, G. Bernardinelli, Z. Anorg. Allg. Chem. 2001, 627(7), 1626-1630. DOI: 10.1002/1521-3749(200107)627:7<1626::AID-ZAAC1626>3.0.CO;2-Q
2000
Similar coordination – different dimensionality: synthesis, single crystal structures and theoretical studies of hydrogen-bonded {[Ca(H2O)2L4]I2}n/∞ (1: L = CH3COOC2H5; 2: L = OC4H8)
K. M. Fromm, G. Bernardinelli, M.-J. Mayor-Lopez, J. Weber, H. Goesmann, Z. Anorg. Allg. Chem. 2000, 626(7), 1685-1691. DOI: 10.1002/1521-3749(200007)626:7<1685::AID-ZAAC1685>3.0.CO;2-M
Multiple expression of molecular information: enforced generation of different supramolecular inorganic architectures by processing of the same ligand information through specific coordination algorithms
D. P. Funeriu, J.-M. Lehn, K. M. Fromm, D. Fenske, Chem. Eur. J. 2000, 6(12), 2103-2111. DOI: 10.1002/1521-3765(20000616)6:12<2103::AID-CHEM2103>3.0.CO;2-S
H-bonded polymer structures of different dimensionality: syntheses and crystal structures of [Ca(DME)n(H2O)m]I2·(DME)x (1: n=3, m=3, x=1; 2: n=2, m=4, x=0) and [Ca{CH3(OCH2)3OCH3}(H2O)4]I2
K. M. Fromm, H. Goesmann, G. Bernardinelli, Polyhedron 2000, 19(15), 1783-1789. DOI: 10.1016/S0277-5387(00)00466-6
On the way to sol-gels: an analysis of the intra- and intermolecular hydrogen bonding in [Ba(OH)I(H2O)4]
K. M. Fromm, H. Goesmann, Acta Cryst. Sect. C 2000, C56(10), 1179-1180. DOI: 10.1107/S0108270100009586
Synthesis and crystal structure of [IBa(OtBu)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium
K. M. Fromm, E. D. Gueneau, H. Goesmann, Chem. Commun. 2000, (22), 2187-2188. DOI: 10.1039/B005638N
1999
Synthesis and crystal structure of Li[{Ca7(µ3-OH)8I6(thf)12}2(µ-I)]·3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol–gels
K. M. Fromm, Chem. Comm. 1999, 17, 1659-1660. DOI: 10.1039/A904560K
1998
Toposelective and chiroselective self-assembly of [2×2] grid-type inorganic arrays containing different octahedral metallic centers
D. M. Bassani, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl. 1998, 37(17), 2364-2367. DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2364::AID-ANIE2364>3.0.CO;2-7
1997
Structural evolution from the solid state to the molecule for BaI2 : synthesis and crystal structures of [BaI2(μ2-OH2)2]3/∞, [BaI2(μ2-OH2)(OC3H6)]2/∞, [BaI2(thf)3]1/∞, and [BaI2(thf)5] · THF
K. M. Fromm, Angew. Chem. 1998, 109(24), 2876-2878; Angew. Chem. Int. Ed. Engl.1998, 36(24), 2799-2801. DOI: 10.1002/anie.199727991
Organometallic tantalum complexes with phosphine, phosphanido and phosphinidene ligands. Syntheses and crystal structures of [Cp′TaCl4[PH2(2, 4, 6-Pri3C6H2)]], [Cp′Ta(μ-PPh2)(PPh2)]2·C7H8 and [Cp′TaCl[μ-P(2, 4, 6-Pri3C6H2)]]2· C7H8(Cp′ =C5H4Me)
G. A. Abdul Hadi, K. M. Fromm, S. Blaurock, S. Jelonek, E. Hey-Hawkins, Polyhedron 1997, 16(4), 721-731. DOI: 10.1016/0277-5387(96)00269-0
Reducible nanoscale molecular rods based on diacetylene-linked poly(phenylthio)-substituted benzenes
M. Mayor, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl. 1997, 36(21), 2370-2372. DOI: 10.1002/anie.199723701
1996
Zintl anions as starting compounds for the synthesis of polynuclear transition metal complexes
R. Ahlrichs, D. Fenske, K. M. Fromm, H. Krautscheid, U. Krautscheid, O. Treutler, Chem. Eur. J. 1996, 2(2), 238-244. DOI: 10.1002/chem.19960020217
1995
Mixed-valence dinuclear molybdenum complexes: synthesis and molecular structure of (Cp°Mo)2(μ-Cl)n(μ-PPh2)3-n (n=1, 0; Cp° = η5-C5Me4Et)
E. Hey-Hawkins, K. M. Fromm, Polyhedron 1995, 14(15/16), 2027-2035. DOI:10.1016/0277-5387(95)00040-Y
Synthesis and molecular structures of molybdenum complexes with phosphido, diphosphanyland diphosphene ligands
E. Hey-Hawkins, K. M. Fromm, Polyhedron 1995, 14(20/21), 2825-2834. DOI:10.1016/0277-5387(95)00220-M
Synthesis and molecular structures of the molybdenum(II) complexes MoCl2(PMe3)2 and [Mo(μ-PPh2)(PPh2)(PMe3)]2
K. M. Fromm, M. Plaikner, E. Hey-Hawkins, Z. Naturforsch. 1995, 50(6), 894-898. DOI: 10.1515/znb-1995-0610
1993
Reaction of cyclopentadienyl substituted molybdenum (V) tetrachlorides with LiPH(2,4,6-But3C6H2) and KPPh2(dioxane)2. Crystal structures of [Cp0Mo(μ-Cl)2]2 and [CpMo2(μ-Cl)3(μ-PPh2)] (Cp0 = C5Me4Et)
K. M. Fromm, E. Hey-Hawkins, Z. anorg. allg. Chem. 1993, 619(2), 261-270. DOI: 10.1002/zaac.19936190207
1992
Synthesis and crystal structure of meso-(1,2,3-tricyclohexyltriphosphine-1,3-diyl)zirconocene (IV), [cyclic] Cp2Zr(PCy-PCy-PCy) (Cp = η5-C5H5 ; Cy = C6H11)
K. M. Fromm, G. Baum, E. Hey-Hawkins, Z. anorg. allg. Chem. 1992, 615, 35-38. DOI: 10.1002/zaac.19926150907