list of publication (pdf)


Complexation Behavior of Pinene–Bipyridine Ligands towards Lanthanides: The Influence of the Carboxylic Arm
A. B. Solea, L. Yang, A. Crochet, K. M. Fromm, C. Allemann, O. Mamula, Chemistry 2022, 4, 1, 18-30. DOI:10.3390/chemistry4010002 Open Access  Special Issue to Celebrate the Life and Work of Alexander von Zelewsky (1936–2021)


Multifunctional Anthracene-Based Ni-MOF with Encapsulated Fullerenes: Polarized Fluorescence Emission and Selective Separation of C70 from C60
S. I. Vasylevskyi, G. Raffy, S. Salentinig, A. Del Guerzo, C. E. Housecroft, K. M. Fromm, D. M. Bassani ACS Appl. Mater. Interfaces 2021, ASAP. DOI: 10.1021/acsami.1c19141

Memorial Issue Dedicated to Dr. Howard D. Flack: The Man behind the Flack Parameter
C. E. Housecroft, K. M. Fromm, Chemistry 2021, 3, 3, 818-820. DOI: 10.3390/chemistry3030058 Open Access

Efficient synthesis of isoindolones by intramolecular cyclisation of pyridinylbenzoic acids
A. B. Solea, S. Wang, X.-S. Xue, A. Crochet, K. M. Fromm, K. N. Houk, O. Mamula, C. Allemann; Org. Biomol. Chem. 2021, 19, 8025-8029. DOI: 10.1039/D1OB01343B

NMR reveals the interplay between SilE and SilB model peptides in the context of silver resistance
L. Babel, M.-H. Nguyen, C. Mittelheisser, M. Martin, K. M. Fromm, O. Walker, M. Hologne; Chem. Comm. 2021, 57, 8726-8729. (cover) DOI: 10.1039/D1CC02597J Open Access

7-OH quinoline Schiff bases: are they the long awaited tautomeric bistable switches ?
A. Georgiev, D. Yordanov, N. Ivanova, V. Deneva, N. Vassilev, F. Kamounah, M. Pittelkow, A. Crochet, K. M. Fromm, L. Antonov; Dyes and Pigment 2021, 195, 109739. DOI:10.1016/j.dyepig.2021.109739

General Chemistry: Large Classes, Mixed Public, Three Languages (A Personal Experience)
K. M. Fromm; Chimia 2021, 75, 39-44. doi:10.2533/chimia.2021.39 Open Access

On the Ni0.75Ti1.5Fe0.5(PO4)3/C NASICON-type electrode material
M. Srout, M. Amou, K. M. Fromm, I. Saadoune; J. Electroanal. Chem. 2021, 880, 114913. DOI: 10.1016/j.jelechem.2020.114913


New Antimicrobial Strategies Based on Metal Complexes
M. Claudel, J. V. Schwarte, K. M. Fromm; Chemistry 2020, 2(4), 849-899. DOI: 10.3390/chemistry2040056 Open Access

Handling (Nano)Silver as Antimicrobial Agent: Therapeutic Window, Dissolution Dynamics, Detection Methods and Molecular Interactions
S.-L. Abram, K. M. Fromm; Chem. Eur. J. 2020, 26, 10948-10971. DOI: 10.1002/chem.202002143 Open Access

A Simple Reaction for DNA Sensing and Chemical Delivery
E. Janett, K.-L. Diep, K. M. Fromm, C. G. Bochet; ACS Sens. 2020, 5, 8, 2338-2343. DOI: 10.1021/acssensors.0c00988

Bimetallic Salen-based compounds and their potential applications
A. Finelli, S.-L. Abram, N. Hérault, A. Crochet, K. M. Fromm; Cryst. Growth Des. 2020, 20,8, 4945-4958. DOI: 10.1021/acs.cgd.9b01610

Isolation of cellulose nanofibers from oryza sativa residues via TEMPO mediated oxidation
E. S. Madivoli, P. G. Kareru, A. N. Gachanja, S. M. Mugo, D. M. Sujee & K. M. Fromm; J. Nat. Fibers 2020. DOI: 10.1080/15440478.2020.1764454

OH group effect in the stator of β-diketone based rotary switches
S. Hristova, F. S. Kamounah, A. Crochet, N. Vassilev, K. M. Fromm, L. Antonov; Chemistry 20202(2), 374-389. (Cover) DOI: 10.3390/chemistry2020024 Open Access

Indirect solvent assisted tautomerism in 4-substituted phthalimide 2-hydroxy-Schiff bases
D. Yordanov, V. Deneva, A. Georgiev, A. Crochet, K. M. Fromm, L. Antonov; Spectroc. Acta A 2020118416. DOI: 10.1016/j.saa.2020.118416

A nano-rattle SnO2@carbon composite anode material for high-energy Li-ion batteries by melt diffusion impregnation
S. Maharajan, N. H. Kwon, P. Brodard, K. M. Fromm; Nanomaterials 2020, 10(4). DOI: 10.3390/nano10040804Open Access

Improvement of the electrochemical performance by partial chemical substitution into the lithium site of titanium phosphate-based electrode materials for lithium-ion batteries: LiNi0.25Ti1.5 Fe0.5(PO4)3
M. Srout, M. El Kazzi, H. Ben Youcef, N. Semlal, K. M. Fromm, I. Saadoune; J. Power Sources 2020, 228114. DOI: 10.1016/j.jpowsour.2020.228114

Li0.5Ni0.5Ti1.5Fe0.5(PO4)3/C electrode material for lithium ion batteries exhibiting faster kinetics and enhanced stability
M. Srout, N. H. Kwon, H. Ben Youcef, N. Semlal, K. M. Fromm, I. Saadoune; ACS Appl. Mater. Interfaces 202012, 16, 18496-18503. DOI: 10.1021/acsami.0c00712

Appropriate Buffers for Studying the Bioinorganic Chemistry of Silver(I)
L. Babel, S. Bonnet-Gomez, K. M. Fromm; Chemistry 20202, 193-202. DOI: 10.3390/chemistry2010012Open Access

Metal Nanoparticle-Microbe Interactions: Synthesis and Antimicrobial Effects
M. R. Khan, K. M. Fromm, T. F. Rizvi, B. Giese, F. Ahamad, R. J. Turner, M. Füeg, E. Marsili, Part. Part. Syst. Charact. 2020, 1900419. DOI: 10.1002/ppsc.201900419

Silver-Containing Titanium Dioxide Nanocapsules for Combating Multidrug-Resistant Bacteria
N. Hérault, J. Wagner, S.-L. Abram, J. Widmer, L. Horvath, D. Vanhecke, C. Bourquin, K. M. Fromm, Int. J. Nanomedicine. 2020; 15:1267-1281. DOI: 10.2147/IJN.S231949 Open Access

Kinetics and Mechanism of Mineral Respiration: How Iron‐Hemes Synchronize Electron Transfer Rates
V. Chabert, L. Babel, M. P. Füeg, M. Karamash, E. S. Madivoli, N. Herault, J. M. Dantas, C. A. Salgueiro, B. Giese, K. M. Fromm, Angew. Chem. Int. Ed., 2020, 59, pp 12331-12336. DOI: 10.1002/anie.201914873
Angew. Chem. (German Ed.): DOI: 10.1002/ange.201914873

Tautomerism and Self-Association in the Solution of New Pinene-Bipyridine and Pinene-Phenanthroline Derivatives
A. B. Solea, I. Cornu, V. Deneva, A. Crochet, K. M. Fromm, L. Antonov, C. Allemann, O. Mamula, Molecules, 2020, 25(2), 298. DOI: 10.3390/molecules2520298 Open Access

Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!
K. M. Fromm, Coord. Chem. Reviews 2020, 408, 213193. DOI: 10.1016/j.ccr.2020.213193


Surface modifications of positive-electrode materials for lithium ion batteries
N. H. Kwon, J. Conder, M. Srout, K. M. Fromm, Chimia, 2019, 73, 880-893. DOI: 10.2533/chimia.2019.880

Sequential multi-target sensor: In3+, Fe2+ and Fe3+ discrimination by anthracene-based probe
A. Finelli, V. Chabert, N. Hérault, A. Crochet, C. Kim, K. M. Fromm, Inorg. Chem., 2019, 58, 20, 13796-13806. DOI: 10.1021/acs.inorgchem.9b01478

New Ni0.5Ti2(PO4)3@C Nasicon‐type electrode material with high rate capability performance for Lithium‐ion batteries: Synthesis and Electrochemical properties
I. Saadoune, M. Srout, N.-H. Kwon, L. Wen, A. Züttel, K. M. Fromm, ChemSusChem, 2019, 12, 1-9. DOI: 10.1002/cssc.201902002

Different coordination abilities of 1,7- and 4,7-phenanthroline in the reactions with copper(II) salts: structural characterization and biological evaluation of the reaction products
N. Lj. Stevanović, T. P. Andrejević, A. Crochet, T. Ilic-Tomic, N. S. Drašković, J. Nikodinovic-Runic, K. M. Fromm, Miloš I. Djuran, Biljana Đ. Glišić, Polyhedron, 2019, 173, 114112. DOI: 10.1016/j.poly.2019.114112

Tautomerism as primary signaling mechanism in metal sensing: the case of amide group
V. Deneva, G. Dobrikov, A. Crochet, D. Nedeltcheva, K. M. Fromm and L. Antonov, Belstein J. Org. Chem. , 2019, 15, 1898-1906. DOI: 10.3762/bjoc.15.185  Open Access

Efficient Perovskite Nanocrystal Light-Emitting Diodes Using Benzimidazole-Substituted Anthracene Derivative as the Electron Transport Material
S. Kumar, T. Marcato, S. Vasylevskyi, J. Jagielski, K. M. Fromm and C. Shih, J. Mater. Chem. C, 2019, 7, 8938-8945. DOI: 10.1039/C9TC02352F.

Compartmentalization of Alkaline Earth Metals in Salen-type Cu- and Ni-Complexes in Solution and in the Solid State
A. Finelli, N. Hérault, A. Crochet, K. M. Fromm, ACS Omega 2019, 4, 6, 10231-10242. DOI: 10.1021/acsomega.9b00365 Open Access

Anion-induced structural diversity of Zn and Cd coordination polymers based on bis-9,10-(pyridine-4-yl)-anthracene, their luminescent properties and highly efficient sensing of nitro derivatives and herbicides
S. I. Vasylevskyi, D. M. Bassani, K. M. Fromm, Inorganic Chemistry 2019, 58, 9, 5646-5653. DOI: 10.1021/acs.inorgchem.8b03628​

Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection
A. Pavic, N. D. Savić, B. Đ. Glišić, A. Crochet, S. Vojnovic, A. Kurutos, D. Stanković, K. M. Fromm, J. Nikodinovic-Runic, M. Djuran, Journal of Inorganic Biochemistry 2019, 195, 149-163. DOI: 10.1016/j.jinorgbio.2019.03.017 

Synthesis and structural analysis of polynuclear silver(I) complexes with 4,7-phenanthroline
I. Stanojević, N. D. Savić, A. Crochet, K. M. Fromm, M. I. Djuran, B. Đ. Glišić, Journal of Serbian Chemical Society 2019, 84, 689-699 . DOI: 10.2298/JSC190226024S  Open Access

Isomerization and aggregation of 2-(2-(2-hydroxy-4-nitrophenyl)hydrazono)-1-phenylbutane1,3-dione: recent evidences from theory and experiment
S. Hristova, F. S. Kamounah, A. Crochet, P. E. Hansen, K. M. Fromm, D. Nedeltcheva, L. Antonov, Journal of Molecular Liquids 2019, 283, 242-248. DOI: 10.1016/j.molliq.2019.03.073 

Synthesis and Applications of Nanocontainers and Nanorattles
S.-L. Abram, P. Yep, K. M. Fromm, Chimia 2019, 73, 12-16. DOI: 10.2533/chimia.2019.12  Open Access

Functional Polymers Through Mechanochemistry
S. Schrettl, D. W. R. Balkenende, C. Calvino, M. Karman, A. Lavrenova, L. N. Neumann, Y. Sagara, E. Verde-Sesto, M. di Giannantonio, Y. C. Simon, K. M. Fromm, M. Lattuada, C. Weder, Chimia 2019, 73, 7-11. DOI: 10.2533/chimia.2019.7  Open Access

Tautomerism in azo dyes: Border cases of azo and hydrazo tautomers as possible NMR reference compounds
V. Deneva; S. Hristova; L. Antonov; A. Lyčka; A. Crochet; K. M. Fromm , Dyes and pigments 2019, 165, 157-163. DOI: 10.1016/j.dyepig.2019.02.015


Metallocene as Mechanophore in Polymers Leads to Metal Ion Release & Oxidation (Highlight)
M. Di Giannantonio, M. A. Ayer, E. Verde-Sesto, M. Lattuada, C. Weder, K. M. Fromm, Chimia 2018, 72, 12, 902. DOI: 10.2533/chimia.2018.902 Open Access

Betti Bases from 4-(3-Pyridazo)-1-naphthol: Synthesis, Coordination Behaviour and Unusual Substitution Reactions
V. B. Kurteva, L. A. Lubenov, B. L. Shivachev, R. P. Nikolova, K. M. Fromm, ChemistrySelect 2018, 3, 12017–12021. DOI: 10.1002/slct.201802745 

Polyaspartamide Functionalized Catechol-Based Hydrogels Embedded with Silver Nanoparticles for Antimicrobial Properties
M. Tan,  Y. Choi, J. Kim, J.-H. Kim, K. M. Fromm, Polymers 2018, 10, 1188-1203. DOI: 10.3390/polym10111188 Open Access

Solid-state structure and anti­microbial and cytotoxicity studies of a cucurbit[6]uril-like Cu6L4 constructed from 3,5-bis­[(1H-tetra­zol-5-yl)meth­yl]-4H-1,2,4-triazol-4-amine
S. I. Vasylevskyi, A. Holzheu, K. M. Fromm, Acta Cryst. C 2018, C74, 1413-1419. DOI: 10.1107/S2053229618013670 Open Access

Mononuclear silver(I) complexes with 1,7-phenanthroline as potent inhibitors of Candida growth
N. D. Savić, S. Vojnovic, B. Đ.Glišić, A. Crochet, A. Pavic, G. V. Janjić, M. Pekmezović, I. M. Opsenica, K. M. Fromm, J, Nikodinovic-Runic, M. I. Djuran, European Journal of Medicinal Chemistry 2018, 156, 760-773. DOI: 10.1016/j.ejmech.2018.07.049 

Alpha-helical folding of SilE models upon Ag(His)(Met) motif formation
V. Chabert, M. Hologne, O. Sénèque, O. Walker, K. M. Fromm, Chem. Comm. 2018, 54, 10419-10422DOI: 10.1039/c8cc03784a  Open Access

With inside cover

Trithiocarbonate-Functionalized PNiPAAm-Based Nanocomposites for Antimicrobial Properties
M. Tan, L. Horvàth, P. S. Brunetto and K. M. Fromm, Polymers 2018, 10(6), 665-690. DOI: 10.3390/polym10060665  Open Access

Triggered metal ion release and oxidation: Ferrocene as new mechanophore in polymers
M. Di Giannantonio, M. A. Ayer, E. Verde-Sesto, M. Lattuada, C. Weder, K. M. Fromm, Angew. Chem., Int. Ed. 2018, online. DOI: 10.1002/anie.201803524

also available in German in Angew. Chem. 2018online. DOI: 10.1002/ange.201803524

Early stage sustainability evaluation of new, nanoscale cathode materials for Li-ion batteries
R. Hischier, N.-H. Kwon, J.-P. Brog, K. M. Fromm, ChemSusChem  2018, 11, 13, 2068-2076. DOI: 10.1002/cssc.201800109 

Amide Neighbouring-​Group Effects in Peptides: Phenylalanine as Relay Amino Acid in Long-​Distance Electron Transfer
J. G. Nathanael, L. F. Gamon, M. Cordes, P. R. Rablen,T. Bally, K. M. Fromm, B. Giese, U. Wille, ChemBioChem201819, 922-926. DOI:10.1002/cbic.201800098 

A Concept for stimulated proton transfer in 1-(phenyldiazenyl)naphtalen-2ols
S. Hristova, V. Deneva, M. Pittelkow, A. Crochet, F. S. Kamounah, K. M. Fromm, P. E. Hansen, L. Antonov, Dyes and Pigments  2018, 156, 91-99.  DOI: 10.1016/j.dyepig.2018.03.070 

Versatile synthesis of chiral 6-​oxoverdazyl radical ligands – new building blocks for multifunctional molecule-​based magnets
A. B. Solea, T. Wohlhauser, P. Abbasi, Y. Mongbanziama, A. Crochet, K. M. Fromm, G. Novitchi, C. Train, M. Pilkington, O. Mamula,  Dalton Trans.  2018, 47, 4785-4789.  DOI: 10.1039/C8DT00840J 

Ag Nanoencapsulation for Antimicrobial Applications
S.-L. Abram, J. Gagnon, M. Priebe, N. Hérault, K. M. Fromm, Chimia  2018, 72, 249-253. cover. DOI: 10.2533/chimia.2018.249 Open Access

Puckering behavior in six new phosphoric triamides containing aliphatic six- and seven-membered ring groups and a database survey of analogous ring-containing structuresB. V. Alviri, M. Pourayoubi, A. Saneei, M. Keikha, A. van der Lee. A. Crochet, A. Ajees, M. Nečas, K. M. Fromm, K. Damodaran, T. A. Jenny,  Tetrahedron  2018, 74, 1, 28-41.  DOI: 10.1016/j.tet.2017.11.030 

Threading Salen-type Cu- and Ni-Complexes into One-Dimensional Coordination Polymers: Solution versus Solid State and the Size Effect of the Alkali Metal Ion
A. Finelli, N. Hérault, A. Crochet,  K. M. Fromm, Cryst. Growth Des.  2018, 2, 1215-1226.  DOI: 10.1021/acs.cgd.7b01769 

WRI1 and DGAT1 regulate tocochromanol metabolism in arabidopsis
S. Pellaud, A. Bory, V. Chabert, J. Romanens, L. Chaisse-Leal, A. V. Doan, L. Frey, A. Gust, K. M. Fromm, L. Mène-Saffrané, New Phytologist  2018217, 245–260.  DOI: 10.1111/nph.14856 Open Access

Cis- and Trans-9,10-di(1H-imidazol-1-yl)-anthracene based coordination polymers of ZnII and CdII: synthesis, crystal structures and luminescence properties
S. I. Vasylevskyi, K. Regeta, A. Ruggi, S. Petoud, C. Piguet, and K. M. Fromm, Dalton Trans., 2018, 47, 596-607.  DOI: 10.1039/C7DT03758A 

The synergistic cooperation of NH⋯O and CH⋯O hydrogen bonds in the structures of three new phosphoric triamides
A. Saneei, M. Pourayoubi, J. P. Jasinski, T. A. Jenny, A. Crochet, K. M. Fromm & A. C. Keeley, Phosphorus, Sulfur, and Silicon and the Related Elements2018, 193, 257-266 . DOI: 10.1080/10426507.2017.1399128 

A Review: Carbon Additives in LiMnPO4- and LiCoO2-Based Cathode Composites for Lithium Ion Batteries
N.-H Kwon, D. Mouck-Makanda,  K. M. Fromm, Batteries 2018, 4, 50-73. DOI: 10.3390/batteries4040050 Open Access


Characteristics and properties of nano-LiCoO2 synthesized by pre-organized single source precursors: Li-ion diffusivity, electrochemistry and biological assessment
J.-P. Brog, A. Crochet, J. Seydoux, M. J. D. Clift, B. Baichette, S. Maharajan, H. Barosova, P. Brodard, M. Spodaryk, A. Züttel, B. Rothen-Rutishauser,  N.-H. Kwon, K. M. Fromm, JNanobiotechnol 2017, 15, 58. DOI: 10.1186/s12951-017-0292-3  Open Access

Influence of the Sacrificial Polystyrene Removal Pathway on the TiO2 Nanocapsule Structure
N. Herault,  K. M. Fromm, Helvetica Chimica Acta 2017, 100(6), e1700014 . DOI: 10.1002/hlca.201700014 

Different molecular assemblies in two new phosphoric triamides with the same C(O)​NHP(O)​(NH)2 skeleton: crystallographic study and Hirshfeld surface analysis
A. Saneei, M. Pourayoubi, T. A. Jenny, A. Crochet, K. M. Fromm, E. S. Shchegravina, Chemical papers 2017, 17, 1809. DOI: 10.1007/s11696-017-0168-x

Influence of anions and solvent molecules on the packing and emission spectra of coordination polymers based on silver ions and an anthracene derivative
J. Chen, N. Voutier, J. Rajabi, A. Crochet, D. M. Bassani, K. M. Fromm, CrysEngComm 2017, 19, 5106-5113. DOI: 10.1039/C7CE00846E 

Model peptide studies of Ag+ binding sites from the silver resistance protein SilE
V. Chabert, M. Hologne, O. Sénèque, A. Crochet, O. Walker, K. M. Fromm, Chem. Commun. 2017, 53, 6105–6108. DOI: 10.1039/c7cc02630g 

Quantitative Nano-characterization of Polymers Using Atomic Force Microscopy
M. Radiom, S. Kozhuharov, P. Kong, M. di Giannantonio,M. Ayer, P. Maroni, A. F. M. Kilbinger, K. M. Fromm, C. Weder, M. Borkovec, Chimia 201771(4), 195-198. DOI: 10.2533/chimia.2017.195 Open Access

Formation of silver nanoparticles by electron transfer in peptides and c-cytochromes
S. I. Vasylevskyi, S. Kracht, P. Corcosa, K. M. Fromm, B. Giese, M. Füeg, Angew. Chem. Int. Ed. 2017, 56, 5926 –5930. DOI: 10.1002/anie.201702621 

Heptacoordinate Co(II) complex: a new architecture for photochemical hydrogen production
F. Lucarini, M. Pastore, S. I. Vasylevskyi, M. Varisco, E. Solari, A. Crochet, K. M. Fromm, F. Zobi, A. Ruggi, Chem. Eur. J. 2017, 23, 6768-6771, DOI: 10.1002/chem.201701427 

Embedding CeO2 nanocontainers in a TiO2 coating on glass surfaces
J. Gagnon, R. A. Caruso, and K. M. Fromm, AIMS Bioengineering 2017,  4(1), 171-178. DOI: 10.3934/bioeng.2017.1.171  Open Access

Antimicrobial silver-filled silica nanorattles with low immunotoxicity in dendritic cells
M. Priebe, J. Widmer, N. Suhartha Löwa, S.-L. Abram, I. Mottas, A.-K. Woischnig, P. S. Brunetto, N. Khanna, C. Bourquin, K. M. Fromm, Nanomedicine: NBM 2017, 13(1), 11-22. DOI: 10.1016/j.nano.2016.08.002 

Nanoparticle shapes of LiMnPO4, Li+-diffusion orientation and diffusion coefficients for high volumetric energy Li+-ion cathodes
N.-H. Kwon, H. Yin, T. Vavrova, J. H.-W. Lim, U. Steiner, B. Grobéty, K. M. Fromm, J. Power Sources 2017, 342, 231-240. DOI: 10.1016/j.jpowsour.2016.11.111 


Going nano for batteries and drug delivery
S.-L. Abram, J.-P. Brog, P. S. Brunetto, A. Crochet, J. Gagnon, N.-H. Kwon, S. Maharajan, M. Priebe, K. M. Fromm, Chimia 2016, 70(9), 661. DOI:10.2533/chimia.2016.661 Open Access

Tandem ring-opening-ring-closing metathesis for functional metathesis catalysts
A. A. Nagarkar, M. Yasir, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Angew. Chem., Int. Ed. 2016, 55, 12343-12346. DOI: 10.1002/anie.201604112  Open Access

Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol
S. Chetioui, D.-A. Rouag, J.-P. Djukic, C. G. Bochet, R. Touzani, C. Bailly, A. Crochet and K. M. Fromm, Acta Cryst. 2016, 72(8), 1093-1098. DOI:10.1107/S205698901601080X Open Access

Synthesis of new polyether ether ketone derivatives with silver binding site and coordination compounds of their monomers with different silver salts
J. Girard, N. Joset, A. Crochet, M. Tan, A. Holzheu, P. S. Brunetto, K. M. Fromm, Polymers 2016, 8(6), 208. DOI:10.3390/polym8060208 

Synthesis, characterization, antibacterial activity and cytotoxicity of hollow TiO2-coated CeO2 nanocontainers encapsulating silver nanoparticles for controlled silver release

Mixed metal multinuclear Cr(III) cage compounds and coordination polymers based on unsubstituted phenolate: design, synthesis, mechanism and properties
A. Crochet, J.-P. Brog, K. M. Fromm, Cryst. Growth Des201616(1), 189-199. DOI: 10.1021/acs.cgd.5b01084

A thermo- and mechanoresponsive cyano-substituted oligo(p-phenylene vinylene) derivative with five emissive states
Y. Sagara, A. Lavrenova, A. Crochet, Y. C. Simon, K. M. Fromm, C. Weder, Chem. Eur. J. 2016 22(13), 4374–4378. DOI: 10.1002/chem.201600272 

Preventing implant-associated infections by silver coating
R. Kuehl, P. S. Brunetto, A.-K. Woischnig, M. Varisco, Z. Rajacic, J. Vosbeck, L. Terracciano, K. M. Fromm, N. Khanna, Antimicrob. Agents Chemother. 2016, 60(4), 2467-2475. DOI: 10.1128/AAC.02934-15 Open Access

The first phosphoramide–mercury(II) complex with a Cl2 Hg–OP[N(C)(C)]3 segment
A. Saneei, M. Pourayoubi, A. Crochet, K. M. Fromm, Acta Crystallogr. C. Struct. Chem201672(3), 230-233. DOI: 10.1107/S2053229616002394  Open Access


Synthesis, X-ray structure and DFT calculation of oxido-vanadium(V) complex with a tridentate Schiff base ligand
I. Sheikhshoaie, S. Y. Ebrahimipour, A. Crochet, K. M. Fromm, Res. Chem. Intermed2015, 41(4), 1881-1891. DOI 10.1007/s11164-013-1317-7 

Nanorattles or yolk-shell nanoparticles-What are they, How are they made, and What are they good for?
M. Priebe, K. M. Fromm, Chem. Eur. J2015, 21(10), 3854-3874. DOI:10.1002/chem.201405285 

Electron transfer in peptides: on the formation of silver nanoparticles
S. Kracht, M. Messerer, M. Lang, S. Eckhardt, M. Lauz, B. Grobety, K. M. Fromm, B. Giese, Angew. Chem. Int. Ed201554(10), 2912-2916.  DOI: 10.1002/anie.201410618 

Controlled tautomeric switching in azonaphthols tuned by substituents on the phenyl ring
L. Antonov, V. DenevaS. SimeonovV. KurtevaA. CrochetK. M. FrommB. ShivachevR. NikolovaM. SavareseC. Adamo, ChemPhysChem, 201516(3), 649-657. DOI: 10.1002/cphc.201402691 

cis-Dioxido-molybdenum(VI) complexes of tridentate ONO hydrazone Schiff base: synthesis, characterization, X-ray crystal structure, DFT calculation and catalytic activity
S. Y. Ebrahimipour, H. Khabazadeh, J. Castro, I. Sheikhshoaie, A. Crochet, K. M. Fromm, Inorg. Chem. Acta 2015, 427, 52-61. Doi:10.1016/j.ica.2014.11.023 

4-Hydroxy-1-naphthaldehydes: proton transfer or deprotonation
Y. Manolova, V. Kurteva, L. Antonov, H. Marciniak, S. Lochbrunner, A. Crochet, K. M. Fromm, F. S. Kamounah, P. E. Hansen, Phys. Chem. Chem. Phys. 201517(15), 10238-10249. DOI: 10.1039/C5CP00870K Open Access

Toxicity and protective effects of cerium oxide nanoparticles (nanoceria) depending on their preparation method, particle size, cell type, and exposure route
J. Gagnon, K. M. Fromm, Eur. J. Inorg. Chem201527, 4510-4517. DOI: 10.1002/ejic.201500643 

Towards cardiolite-inspired carbon monoxide releasing molecules – reactivity of d4, d5 rhenium and dmanganese carbonyl complexes with isocyanide ligands
E. Kottelat, V. Chabert, A. Crochet, K. M. Fromm, F. Zobi, Eur. J. Inorg. Chem201534, 5628-5638. DOI: 10.1002/ejic.201500756 

Layer-by-layer grown scalable redox-active ruthenium-based molecular multilayer thin films for electrochemical applications and beyond
V. Kaliginedi, H. Ozawa, A. Kuzume, S. Maharajan, I. V. Pobelov, N.-H. Kwon, M. Mohos, P. Broekmann, K. M. Fromm, M.-A. Haga, T. Wandlowski, Nanoscale 2015, 7(42), 17685–17692. DOI: 10.1039/c5nr04087f  Open Access

Nanomaterials meet Li-ion batteries
N.-H. Kwon, J.-P. Brog, S. Maharajan, A. Crochet, K. M. Fromm, Chimia 201569(12), 734-736. DOI: 10.2533/chimia.2015.734  Open Access

Construction of polynuclear lanthanide (Ln = DyIII, TbIII, and NdIII) cage complexes using pyridine–pyrazole-based ligands: versatile molecular topologies and SMM behavior
S. Bala, M. S. Bishwas, B. Pramanik, S. Khanra, K. M. Fromm, P. Poddar, R. Mondal, Inorg. Chem. 2015, 54 (17), 8197–8206. DOI: 10.1021/acs.inorgchem.5b00334 

Integrating silver compounds and nanoparticles into ceria nanocontainers for antimicrobial applications
J. Gagnon, M. J. D. Clift, D. Vanhecke, D. A. Kuhn, P. Weber, A. Petri-Fink, B. Rothen-Rutishauser, K. M. Fromm, J. Mat. Chem. B 2015, 3(9), 1760-1768. DOI: 10.1039/C4TB02079K  Open Access


Investigation on the growth and characterization of novel creatinium malate single crystal
S. Mathuri, M. Kayalvizhi, G. Vasuki, R. Ramesh Babu, K. Ramamurthi, A. Crochet, K. M. Fromm, Chem. Sci. Rev. Lett. 2014, 3(12), 1208-1218. ISSN 2278-6783 Open Access

One-pot synthesis and catalytic properties of encapsulated silver nanoparticles in silica nanocontainers
M. Priebe, K. M. Fromm, Particles and Particle Systems Characterization 201431(6), 645-651. DOI: 10.1002/ppsc.201300304 

New antimicrobial and biocompatible implant coating with synergic silver–vancomycin conjugate action
M. Varisco, N. Khanna, P. S. Brunetto, K. M. Fromm, ChemMedChem. 2014,9(6), 1221-1230.  DOI: 10.1002/cmdc.201400072 

Impact of composite structure and morphology on electronic and ionic conductivity of carbon contained LiCoO2 cathode
N.-H. Kwon, H. Yin, P. Brodard, C. Sugnaux, K. M. Fromm, Electrochim. Acta 2014134, 215-221. DOI:10.1016/j.electacta.2014.04.121

Synthesis, crystal structure and antimicrobial activities of di ((E)-2-(pyridine-2-ylmethylene)hydrazinecarboxamide) cobalt(II) dichloride trihydrate
J. Novina, G. Vasuki, M. Suresh, M. S. A. Padusha, K. M. Fromm, A. Crochet, Phys. Science Inter. J. 20144, 816-824. DOI: 10.9734/PSIJ/2014/7803  Open Access

A new mixed-ligand copper(II) complex of (E)-N’-(2-hydroxybenzylidene)acetohydrazide: synthesis, characterization, NLO behavior, DFT calculation and biological activities
S. Y. Ebrahimipour, I. Sheikhshoaie, A. Crochet, M. Khaleghi, K. M. Fromm, J. Mol. Struct. 20141072, 267-276. DOI:10.1016/j.molstruc.2014.05.024 


pH-Dependent coordination of AgI ions by histidine: experiment, theory, and a model for SilE
L. Mirolo, T. Schmidt, S. Eckhardt, M. Meuwly, K. M. Fromm, Chem. Eur. J. 201319(5), 1754-1761.  DOI: 10.1002/chem.201201844 

J. J. Novina, G. Vasuki, C. Muthukumar, A. Sabastiyan, A. Crochet, K. M. Fromm, Acta Cryst. 201369(1), o45. DOI:10.1107/S1600536812049343  Open Access

Ethyl 5-methoxy-2-trifluoromethyl-1H-indol-3-carboxyl-ate
A. Crochet, I. Alimi, C. G. Bochet, K. M. Fromm, Acta Cryst. 201369(3), o339. DOI:10.1107/S1600536813002614  Open Access

Barium bright and heavy
K. M. Fromm, Nature Chem. 20135(2), 146. DOI:10.1038/nchem.1551  Open Access

Ring a bell: disubstituted calix[4]arene as ligand for transition metal chlorides
A. Crochet, K. M. Fromm, Polyhedron 201352, 610-616. DOI:10.1016/j.poly.2012.08.004 

Rings, chains and helices: new antimicrobial silver coordination compounds with (iso-)nicotinic acid derivatives
I. Chevrier, J. L. Sagué, P. S. Brunetto, N. Khanna, Z. Rajacic, K. M. Fromm, Dalton Trans. 2013, 42(1), 217-231. DOI: 10.1039/C2DT31259J 

Kinetics of ion transport through supramolecular channels in single crystals
C. D. Assouma, A. Crochet, Y. Chérémond, B. Giese, K. M. Fromm, Angew. Chem. Int. Ed. 2013, 52(17), 4682-4685. DOI: 10.1002/anie.201208195 

CFA-2 and CFA-3 (coordination framework Augsburg University-2 and -3); novel MOFs assembled from trinuclear Cu(I)/Ag(I) secondary building units and 3,3’,5,5’-tetraphenyl-bipyrazolate ligands
M. Grzywa, C. Gessner, D. Denysenko, B. Bredenkötter, F. Gschwind, K. M. Fromm, W. Nitek, E. Klemm, D. Volkmer, Dalton Trans. 201342(19), 6909-6921.  DOI: 10.1039/C3DT32302A 

Development of a polystyrene sulfonate/silver nanocomposite with self-healing properties for biomaterial applications
J. Girard, P. S. Brunetto, O. Braissant, Z. Rajacic, N. Khanna, R. Landmann, A. U. Daniels, K. M. Fromm, C. R. Chim. 201316(6), 550-556. DOI:10.1016/j.crci.2013.04.010  Open Access

Silver coordination polymers with isonicotinic acid derived short polyethylene gylcol – Synthesis, structures, anion effect and solution behavior
K. M. Fromm, J. L. Sagué, A. Y. Robin, Inorg. Chim. Acta 2013403, 2-8.  DOI:10.1016/j.ica.2012.12.021 

A family of immobilizable chiral bis(pinenebipyridine) ligands
A. Pöllnitz, R. Skupienski, H. Stoeckli-Evans, A. Crochet, A. Silvestru, K. M. Fromm, O. Mamula, Synlett 201324(19), 2555-2558.  DOI: 10.1055/s-0033-1339847 

Bioinorganic chemistry of silver: its interactions with amino acids and peptides
K. M. Fromm, Chimia 201367(12), 851-854. DOI:10.2533/chimia.2013.851  Open Access

Controlled tautomerism – switching caused by an “underground” anionic effect
L. Antonov, V. Deneva, V. Kurteva, D. Nedeltcheva, A. Crochet, K. M. Fromm, RSC Advances 20133(47), 25410-25416 . DOI: 10.1039/C3RA45326J 

Polymorphism, what it is and how to identify it: a systematic review

J.-P. Brog, C.-L- Chanez, A. Crochet, K. M. Fromm, RSC Advances 2013, 3(38), 16905-16931.  DOI: 10.1039/C3RA41559G 

Nanobio-silver: its interactions with peptides and bacteria, and its uses in medicine
S. Eckhardt, P. S. Brunetto, J. Gagnon, M. Priebe, B. Giese, K. M. Fromm, Chem. Rev.2013, 113(7), 4708-4754. DOI: 10.1021/cr300288v

Silver coordination compounds with antimicrobial properties
K. M. Fromm, Appl. Organomet. Chem. 2013, 12, 683-687. DOI: 10.1002/aoc.3047


Tautomerism in 1-phenylazo-4-naphthols: experimental results vs. quantum-chemical predictions
L. Antonov, V. Kurteva, A. Crochet, L. Mirolo, K. M. Fromm, S. Angelova, Dyes and Pigments 201292(1), 714-723. DOI:10.1016/j.dyepig.2011.06.026 

Switching azonaphthols containing a side chain with limited flexibility. Part 1. Synthesis and tautomeric properties
V. B. Kurteva, L. M. Antonov , D. V. Nedeltcheva, A. Crochet, K. M. Fromm, R. P. Nikolova, B. L. Shivachev, M. S. Nikiforova, Dyes and Pigments 201292(3), 1266-1277. DOI:10.1016/j.dyepig.2011.07.013 

Synthesis and characterization of new pentacoordinate iron based aryloxide complexes
Y. Chérémond, A. Crochet, K. M. Fromm, Eur. J. Inorg. Chem. 2012, 2012(16), 2725-2730. DOI: 10.1002/ejic.201101054 

Effect of increasing ligand length on the structure of silver complexes
F. Gschwind, K. M. Fromm, CrystEngComm 201214(11), 4008-4015. DOI: 10.1039/C2CE25110H 

A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid [Bmim][N(Tf)2]
Z.-L. Xie, H.-B. Xu, A. Gessner, M. U. Kumke, M. Priebe, K. M. Fromm, A. Taubert, J. Mat. Chem. 201222(16), 8110-8116.  DOI: 10.1039/C2JM15862K 

Enhanced electrochemical performance of < 30 nm thin LiMnPO4 nanorods with a reduced amount of carbon as a cathode for lithium ion batteries
N. H. Kwon, K. M. Fromm, Electrochim. Acta 201269, 38-44. DOI:10.1016/j.electacta.2012.02.040 

Single crystal to single crystal polymorphic phase transition of a silver nitrate 24-crown-8 complex and its pseudo-polymorphism
J. Girard, K. M. Fromm, CrystEngComm 201214(20), 6487-6491. DOI: 10.1039/C2CE25875G 

The influence of dipole moments on the mechanism of electron transfer through helical peptides
M. Lauz, S. Eckhardt, K. M. Fromm, B. Giese, PhysChemChemPhys 201214(40), 13785-13788. DOI: 10.1039/C2CP41159H 

A comparative study of (poly)ether adducts of alkaline earth iodides ­ an overview including new compounds
W. Maudez, K. M. Fromm, Z. Anorg. Allg. Chem. 2012638(11), 1810-1819. DOI: 10.1002/zaac.201200231 

Antibacterial properties of nanoparticles
M. J. Hajipour, K. M. Fromm, A. Akbar Ashkarran, D. Jimenez de Aberasturi, I. R. de Larramendi, T. Rojo,  V. Serpooshan, W. J. Parak, M. Mahmoudi, Trends Biotechnol. 201230(10), 499-511. DOI:10.1016/j.tibtech.2012.06.004 

Efficient amine end-functionalization of living ring-opening metathesis polymers
A. A. Nagarkar, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Macromolecules 2012, 45(11), 4447-4453. DOI: 10.1021/ma300602p 

Preparation of imidazolidin-4-ones and their evaluation as hydrolytically cleavable precursors for the slow release of bioactive volatile carbonyl derivatives
A. Trachsel, B. Buchs, G. Godin, A. Crochet, K. M. Fromm, A. Herrmann, Eur. J. Org. Chem. 201214, 2837-2854. DOI: 10.1002/ejoc.201200081 


Give silver a shine
K. M. Fromm, Nature Chemistry 20113(2), 178. DOI:10.1038/nchem.970  Open Access

Electron transfer in peptides: the influence of charged amino acids
J. Gao, P. Müller, M. Wang, S. Eckhardt, M. Lauz, K. M. Fromm, B. Giese, Angew. Chem., Int. Ed. 2011, 50(8), 1926-1930.  DOI10.1002/anie.201003389 

In vitro biocompatibility of new silver(I) coordination compound coated-surfaces for dental implant applications
P. S. Brunetto, T. Vig Slenters, K. M. Fromm, Materials 20114, 355-367. DOI:10.3390/ma4020355  Open Access

Polymorph of dibenzo-24-crown-8 and its mercury complex
A. Crochet, E. Kottelat, A. Fleury, M. Neuburger, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(6), 672-675. DOI: 10.1002/zaac.201100065 

A. Crochet, K. M. Fromm, V. Kurteva, L. Antonov, Acta Cryst E, Struct Reports Online 2011E67(4), o993.  ISSN 1600-5368 Open Access

Tetraethylene glycol adducts of alkaline earth halides
F. Gschwind, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(12), 1871-1879.  DOI: 10.1002/zaac.201100192 

Coordination networks of mercury(II) halides and polyether ligand
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(14-15), 2089-2092.  DOI: 10.1002/zaac.201100283 

Nanoencapsulation of anti-microbial drugs
J. Gagnon, P. Weber, K. M. Fromm, Europ. Cells & Materials 201121(2), 49. ISSN 1473-2262


From alkaline earth ion aggregates via transition metal coordination polymer networks towards heterometallic single source precursors for oxidic materials
F. Gschwind, A. Crochet. W. Maudez, K. M. Fromm, Chimia 201064(5), 299-302. DOI: 10.2533/chimia.2010.299  Open Access

Polyether adducts of d-block metal compounds as starting materials for new cluster compounds
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2010636(8), 1484-1496. DOI: 10.1002/zaac.201000022 

Of chains and rings: synthetic strategies and theoretical investigations for tuning the structure of silver coordination compounds and their applications
T. Vig Slenters, J. L. Sagué, P. S. Brunetto, S. Zuber, A. Fleury, L. Mirolo, A. Y. Robin, M. Meuwly, O. Gordon, R. Landmann, A. U. Daniels, and K. M. Fromm, Materials 20103(5), 3407-3429. DOI:10.3390/ma3053407  Open Access

Tautocrowns: a concept for a sensing molecule with an active side-arm
L. M. Antonov, V. B. Kurteva, S. P. Simeonov,  V. V. Deneva, A. Crochet, K. M. Fromm, Tetrahedron 201066(24), 4292-4297.  DOI:10.1016/j.tet.2010.04.049 

Silver coordination polymers for prevention of implant infection: thiol interaction, impact on respiratory chain enzymes, and hydroxyl radical induction
O. Gordon, T. Vig. Slenters, P. S. Brunetto, A. E. Villaruz, D. E. Sturdevant, M. Otto, R. Landmann, K. M. Fromm, Antimicrob. Agents Chemother. 201054(10), 4208-4218.  DOI: 10.1128/AAC.01830-09  Open Access

Synthesis, X-ray crystal structure, thermal and solution studies of a centrosymmetric metal-organic polymer based on proton transfer methodology
H. Eshtiagh-Hosseini, A. Hassanpoor, N. Alfi, M. Mirzaei, K. M. Fromm, A. Shokrollahi, F. Gschwind, E. Karami, J. Coord. Chem. 201063(18), 3175-3186.  DOI: 10.1080/00958972.2010.508518 

Excimer formation in crystalline and nanostructured coordination polymers
J. Chen, A. Neels, K. M. Fromm, Chem. Commun. 2010, 46(43), 8282-8284.  DOI: 10.1039/C0CC03011B 

On the chemical synthesis of titanium nanoparticles from ionic liquids
A. A. Ayi, V. Khare, P. Strauch, J. Girard, K. M. Fromm, A. Taubert, Monatshefte für Chemie 2010141(12), 1273-1278.  DOI: 10.1007/s00706-010-0403-4  Open Access

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure
H. Eshtiagh‐Hosseini, M. Mahjoobizadeh, M. Mirzaei, K. M. Fromm, A. Crochet, Eur. J. Chem. 2010, 1(3), 179-181. DOI:10.5155/eurjchem.1.3.179‐181.44 Open Access

Coordination polymer networks: an alternative to classical polymers?
K. M. Fromm, J. L. Sagué, L. Mirolo, Macromol. Symp. 2010, 291–292, 75–83. DOI: 10.1002/masy.201050509 


Silver-nanoparticle formation in different sizes induced by peptides identified within split-and-mix libraries
K. Belser, T. Vig Slenters, C. Pfumbidzai, G. Upert, L. Mirolo, K. M. Fromm, H. Wennemers, Angew. Chem. Int. Ed. 2009, 48(20), 3661-3664. DOI: 10.1002/anie.200806265 

The heterometallic clusters of trivalent rare earth metals of [Ln(OPh)6{Li(dme)}3] with Ln = Eu and Sm
W. Maudez, K. M. Fromm, Helv. Chim. Acta 2009, 92(11), 2349-2356. DOI: 10.1002/hlca.200900171 

Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol
D. Nedeltcheva, F. S. Kamounah, S. Fadhil, L. Mirolo, K. M. Fromm, L. Antonov, Dyes and Pigments 200983(1), 121-126.  DOI:10.1016/j.dyepig.2009.04.002 

Multitopic ligand design: a concept for single-source precursors
F. Gschwind, O. Sereda, K. M. Fromm, Inorg. Chem. 200948(22), 10535-10547. DOI: 10.1021/ic9009064 

Getting hooked on supramolecular coordination chemistry
K. M. Fromm, Chimia 2009,  63(12), 858-859. DOI:10.2533/chimia.2009.858  Open Access


Antimicrobial coatings for implant surfaces
P. S. Brunetto, K. M. Fromm, Chimia 200862(4), 249-252. DOI:10.2533/chimia.2008.249  Open Access

Silver nanoparticle engineering via oligovaline organogels
A. Mantion, A. G. Guex, A. Foelske, L. Mirolo, K. M. Fromm, M. Painsi, A. Taubert, Soft Matter 20084(3), 606-617.  DOI: 10.1039/B712826F 

Amino acids in iron oxide mineralization: (incomplete) crystal phase selection is achieved even with single amino acids
A. Mantion, F. Gozzo, B. Schmitt, W. B. Stern, Y. Gerber, A. Y. Robin, K. M. Fromm, M. Painsi, A. Taubert, J. Phys. Chem. C 2008112(32), 12104-12110. DOI: 10.1021/jp075449u 

Silver coordination compounds as light-stable, nano-structured and anti-bacterial coatings for dental implant and restorative materials
T. Vig Slenters, I. Hauser-Gerspach, A. U. Daniels, K. M. Fromm, J. Mat. Chem. 200818(44), 5359–5362. DOI: 10.1039/B813026D 

Counterion effect on the formation of coordination polymer networks between AgNO3 and L (2,2′-oxybis(ethane-2,1-diyl) diisonicotinate). Part 2
J. L. Sagué, M. Meuwly, K. M. Fromm, CrystEngComm 200810(11), 1542-1549.  DOI: 10.1039/B803158D 

Combating implant infections. Remarks by a women’s team
C. R. Arciola, N. Balaban, L. Baldassarri, K. Fromm, G. M. Hansch, U. Obst, E. Presterl, S. Stefani, J. Verran, L. Visai, The International journal of artificial organs 200831(9), 858-864.  ISSN:0391-3988

Coordination polymer networks with s-block metal ions
K. M. Fromm, Coord. Chem. Rev.,2008, 252(8+9), 856-885. DOI: 10.1016/j.ccr.2007.10.032


Structure–property relationships: Polymorphism, solvates, and clay behavior in the one-dimensional coordination polymer chains [Ag(L)(NO3)](H2O)n, L = ethanediyl bis(isonicotinate), n= 0, and 2
A. Y. Robin, J. L. Sague Doimeadios, A. Neels, T. Vig Slenters,  K. M. Fromm, Inorg. Chim. Acta 2007, 360(1), 212-220.  DOI:10.1016/j.ica.2006.07.086 

Analogy of the coordination chemistry of alkaline earth metal and lanthanide Ln2+ ions: the isostructural zoo of mixed metal cages [IM(OtBu)4{Li(thf)}4(OH)] (M=Ca, Sr, Ba, Eu), [MM’6(OPh)8(thf)6] (M=Ca, Sr, Ba, Sm, Eu, M’=Li, Na), and their derivatives with 1,2-dimethoxyethane
W. Maudez, M. Meuwly, K. M. Fromm, Chem. Eur. J. 200713(29), 8302 – 8316.  DOI: 10.1002/chem.200700597 

From simple rings to one-dimensional channels with calix[8]arenes, water clusters and alkali metal ions

R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Tetrahedron 2007, 63(44), 10751-10757.  DOI:10.1016/j.tet.2007.07.048 

Transport properties of solid state crown ether channel systems
K. M. Fromm, R. D. Bergougnant, Solid State Sciences 20079(7), 580-587. DOI:10.1016/j.solidstatesciences.2007.04.012 


Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies
M. Dulak, R. Bergougnant, K. M. Fromm, H. R. Hagemann, A. Y. Robin, T. A. Wesolowski, Spectrochim. Acta Mol. Biomol. Spectrosc. 2006, 64A(2), 532–548. DOI:10.1016/j.saa.2005.07.060 

[Ag(isonicotinamide)2NO3]2– a stable form of silver nitrate
T. Dorn, K. M. Fromm, C. Janiak, Aust. J. Chem. 200659(1), 22-25.  DOI: 10.1071/CH05270 

On the coordination behaviour of NO3 in coordination compounds with Ag+. Part 1. Solubility effect on the formation of coordination polymer networks between AgNO3 and L(L = ethanediylbis(isonicotinate) as a function of solvent
A. Y. Robin, J. L. Sagué, K. M. Fromm, CrystEngComm, 20068, 403-416.  DOI: 10.1039/B517191A

Di-Benzo-18-crown-6 and its derivatives as ligands in the search for ion channels
K. M. Fromm, R. D. Bergougnant, A. Y. Robin, Z. Anorg. Allg. Chem. 2006632(5), 828-836. DOI: 10.1002/zaac.200500470 

Substitution reactions on alkaline earth metal iodides: a large anionic Sr12-aggregate [{Sr6(O)(μ3-I)(I)2(OtBu)7(thf)3}2(μ-I)]
W. Maudez, T. Vig-Slenters, L. Mirolo, A. Fleury, K. M. Fromm, Main Group Chemistry 20065(1), 41-49.  DOI: 10.1080/10241220600841862 

Substitution reactions on CaI2: synthesis of mixed metal lithium-calcium-phenolates, and cluster transformation as a function of solvent
W. Maudez, D. Häussinger, K. M. Fromm, Z. Anorg. Allg. Chem. 2006, 632(14), 2295-2298. DOI: 10.1002/zaac.200600170 

Film-forming polymers containing in the main-chain dibenzo crown ethers with aliphatic (C10-C16), aliphatic-aromatic, or oxyindole spacers
M. G. Zolotukhin, M.C. G. Hernández, A. M. Lopez, L. FominaG. Cedillo, A. Nogales, T. Ezquerra, D. RuedaH. M. Colquhoun, K. M. Fromm, A. Ruiz-Treviño, M. Ree, Macromolecules 2006, 39(14), 4696-4703. DOI: 10.1021/ma052148e 

The first two-dimensional polycatenane: a new type of robust network obtained by Ag-connected one-dimensional polycatenanes
J. L. Sagué, K. M. Fromm, Cryst. Growth Des. 2006, 6(7), 1566-1568.  DOI: 10.1021/cg060255+ 

A structural study of copper(II) carboxylates: crystal structure and physical characterisation of [Cu2(2-bromopropanoato)4(caffeine)2]
F. Valach, M. Melnik, G. Bernardinelli, K. M. Fromm, J. Chem. Cryst. 200636(9), 571-580.  DOI: 10.1007/s10870-006-9102-8 

Coordination polymer networks with O- and N-donors: what they are, why and how they are made
A. Y. Robin, K. M. Fromm, Coord. Chem. Rev. 2006, 250(15+16), 2127-2157. DOI: 10.1016/j.ccr.2006.02.013

Recent advances in tailoring the aggregation of heavier alkaline earth metal halides, alkoxides and aryloxides from non-aqueous solvents
K. M. Fromm, Dalton Transactions, 2006, 43, 5103-5112. DOI: 10.1039/B611042H


Recent advances in the chemistry of “clusters” and coordination polymers of alkali, alkaline earth metal and group 11 compounds
K. M. Fromm, E. D. Gueneau, A. Y. Robin, W. Maudez, J. Sague, R. Bergougnant, Z. Anorg. Allg. Chem. 2005631(10), 1725-1740.  DOI: 10.1002/zaac.200500079 

Chiral S-1,1’-bi-2-naphthol (S-BINOL) as a synthon for supramolecular hydrogen-bonded {(S-BINOLATn-)(S-BINOL)n}-strands with naphthyl-paneled cavities or channels for a Cd(NH3)4-fragment (n = 2) or [Ag(NH3)2]+ (n = 1). Part 2.
B. Paul, C. Näther, K. M. Fromm, C. Janiak, CrystEngComm. 20057(51), 309–319.  DOI: 10.1039/B502202A 

“Hooked on” calix[8]arenes: a (H2O)10-cluster with an unprecedented structure
R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Cryst. Growth Des. 20055(5), 1691-1694.  DOI: 10.1021/cg050201k 

Concomitant crystallization of two polymorphs – a ring and a helix: concentration effect on supramolecular polymorphism or isomerism
K. M. Fromm, J. L. Sagué Doimeadios, A. Y. Robin, Chem. Commun. 200536, 4548-4550.  DOI: 10.1039/B506389B 


1[M(μ-O2C-C6H4-CO2)(NH3)2] (M = Cu, Cd; O2C-C6H4-CO2 = benzene-1,4-dicarboxylate, terephthalate): 1D coordination polymers with strong inter-chain hydrogen bonding
B. Paul, B. Zimmermann, K. M. Fromm, C. Janiak, Z. Anorg. Allg. Chem. 2004, 630(11), 1650-1654.  DOI: 10.1002/zaac.200400240 

Molecular paneling of rac-1,1’-bi-2-naphthol/~ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4or 6]2+complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2-(BINOL)2}-strands
B. Paul, C. Näther, B. Walfort, K. M. Fromm, B. Zimmermann, H. Lang, C. Janiak, CrystEngComm 20046(51), 293-297.  DOI: 10.1039/B410933C 

How many structures are there for {[AgL](NO3)(H2O)n}? Water-content dependent variations in the structure of {[AgL](NO3)(H2O)n}, n = 0, 1, 2; L = ethanediyl bis(isonicotinate)
A. Y. Robin, M. Meuwly, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 20046(60), 336–343. DOI: 10.1039/B413232G 

Structures of alkali and alkaline earth metal clusters with oxygen donor ligands
K. M. Fromm, E. D. Gueneau, Polyhedron2004, 23(9), 1479-1504. DOI : 10.1016/j.poly.2004.04.014


Synthesis and structural analysis of the polymetallated alkali calixarenes [M4(p-tert-butylcalix[4]arene-4H)(thf)x]2·n THF (M = Li, K; n = 1 or 6; x = 4 or 5) and [Li2(p-tert-butylcalix[4]arene-2H)(H2O)(μ-H2O)(thf)]·3THF
E. D. Gueneau, K. M. Fromm, H. Goesmann, Chem. Eur. J. 20039(2), 509-514. DOI: 10.1002/chem.200390053 

“One-dimensional water” and “one-dimensional acid”: synthesis and the unique crystal structure of [(H2O)⊂(DB18C6)(μ2-H2O)2/2][(H3O)⊂(DB18C6)(μ2-H2O)2/2]I3 (DB18C6 = dibenzo-18-crown-6)
K. M. Fromm, E. D. Gueneau, H. Goesmann, C. G. Bochet, Z. Anorg. Allg. Chem. 2003629(4), 597-600.  DOI: 10.1002/zaac.200390101 

Understanding the formation of new clusters of alkali and alkaline earth metals: a new synthetic approach, single crystal structures and theoretical calculations
K. M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, H. Chermette, J. Am. Chem. Soc. 2003125(12), 3593-3604.  DOI: 10.1021/ja0205737 

Oxygen donor stabilized alkaline earth metal iodides
K M. Fromm, Chimia 200357(4), 175-178.  CODEN:CHIMAD; ISSN:0009-4293

Polar molecular precursors for alkali and alkaline earth metal clusters and low-dimensional polymer structures: the solid state structures of [CaI(dme)3]I, and cis-[SrI2(diglyme)2] (dme = CH3OC2H4OCH3; diglyme = CH3(OC2H4)2OCH3)
K. M. Fromm, W. Maudez, Eur. J. Inorg. Chem. 200318, 3440-3444. DOI: 10.1002/ejic.200300241 

Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)
A. Y. Robin, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 20035(71), 405–410.  DOI: 10.1039/B309410C 

Coordination compounds
K. M. Fromm, Kirk-Othmer Encyclopedia of Chemical Technology, Copyright © 2003 by John Wiley & Sons, Inc. DOI: 10.1002/0471238961.0315151801180308.a01.pub2


Crown ethers as stabilizing ligands for asymmetric coordination: synthesis, crystal structure, and physical properties of [Na ⊂ (DB18C6)I(thf)], [Na ⊂ (DB18C6)I(1,3-dioxolane)], and [Na ⊂ (DB24C8)]I (DB18C6 = Dibenzo-18-crown-6, DB24C8 = Dibenzo-24-crown-8)
K. M. Fromm, E. D. Gueneau, J.-P. Rivera, G. Bernardinelli, H. Goesmann, Z. Anorg. Allg. Chem. 2002628(1), 171-178.  DOI: 10.1002/1521-3749(200201)628:1<171::AID-ZAAC171>3.0.CO;2-K 

Ionic or covalent? Can some first hints be derived from the solid state structures of alkaline earth metal halide adducts?
K. M. Fromm, CrystEngComm. 20024(57), 318-322.  DOI: 10.1039/B201975M 

Recent advances in the chemistry of clusters and inorganic polymers of alkali and alkaline earth metal compounds
K. M. Fromm, Chimia 200256(12), 676-680. CODEN:CHIMAD; ISSN:0009-4293 Open Access

Electron transfer through bridging molecular structures
M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Ann. N. Y. Acad. Sci. 2002, 960, 16-28. DOI: 10.1111/j.1749-6632.2002.tb03022.x


Electron transfer through molecular bridges between reducible pentakis(thiophenyl)benzene subunits
M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Chem. Eur. J. 20017(6), 1266-1272.  DOI: 10.1002/1521-3765(20010316)7:6<1266::AID-CHEM1266>3.0.CO;2-S 

Hydrogen-bonding and metal-ion mediated self-assembly of a nanoporous crystal lattice
D. G. Kurth, K. M. Fromm, J.-M. Lehn, Eur. J. Inorg. Chem. 2001, (6), 1523-1526.  DOI: 10.1002/1099-0682(200106)2001:6<1523::AID-EJIC1523>3.0.CO;2-2 

A logical concept of structure prediction derived from supramolecular polymers of alkaline earth metal halides formed by hydrogen bonding and complexation of the metal ion
K. M. Fromm, Chem. Eur. J. 20017(10), 2236-2244.  DOI: 10.1002/1521-3765(20010518)7:10<2236::AID-CHEM2236>3.0.CO;2-S 

Synthesis and crystal structure of the one-dimensional polymer compound 1{[Ba(OTf)2(thf)3]2[Ba(OTf)2(thf)2]}(OTf = CF3SO3) – excerpts from a three-dimensional structure as an access to new materials?
K. M. Fromm, G. Bernardinelli, Z. Anorg. Allg. Chem. 2001627(7), 1626-1630.  DOI: 10.1002/1521-3749(200107)627:7<1626::AID-ZAAC1626>3.0.CO;2-Q 


Similar coordination – different dimensionality: synthesis, single crystal structures and theoretical studies of  hydrogen-bonded {[Ca(H2O)2L4]I2}n/∞ (1: L = CH3COOC2H5; 2: L = OC4H8)
K. M. Fromm, G. Bernardinelli,  M.-J. Mayor-Lopez, J. Weber, H. Goesmann, Z. Anorg. Allg. Chem. 2000, 626(7), 1685-1691.  DOI: 10.1002/1521-3749(200007)626:7<1685::AID-ZAAC1685>3.0.CO;2-M 

Multiple expression of molecular information: enforced generation of different supramolecular inorganic architectures by processing of the same ligand information through specific coordination algorithms
D. P. Funeriu, J.-M. Lehn, K. M. Fromm, D. Fenske, Chem. Eur. J. 20006(12), 2103-2111. DOI: 10.1002/1521-3765(20000616)6:12<2103::AID-CHEM2103>3.0.CO;2-S 

H-bonded polymer structures of different dimensionality: syntheses and crystal structures of [Ca(DME)n(H2O)m]I2·(DME)x (1: n=3, m=3, x=1; 2: n=2, m=4, x=0) and [Ca{CH3(OCH2)3OCH3}(H2O)4]I2
K. M. Fromm, H. Goesmann, G. Bernardinelli,  Polyhedron 200019(15), 1783-1789. DOI: 10.1016/S0277-5387(00)00466-6 

On the way to sol-gels: an analysis of the intra- and intermolecular hydrogen bonding in [Ba(OH)I(H2O)4]
K. M. Fromm, H. Goesmann, Acta Cryst. Sect. C 2000, C56(10), 1179-1180. DOI: 10.1107/S0108270100009586  Open Access

Synthesis and crystal structure of [IBa(OtBu)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium
K. M. Fromm, E. D. Gueneau, H. Goesmann, Chem. Commun. 2000, (22), 2187-2188. DOI: 10.1039/B005638N 


Synthesis and crystal structure of Li[{Ca73-OH)8I6(thf)12}2(µ-I)]·3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol–gels
K. M. Fromm, Chem. Comm. 199917, 1659-1660.  DOI: 10.1039/A904560K  Open Access


Toposelective and chiroselective self-assembly of [2×2] grid-type inorganic arrays containing different octahedral metallic centers
D. M. Bassani, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl1998, 37(17), 2364-2367.  DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2364::AID-ANIE2364>3.0.CO;2-7 


Structural evolution from the solid state to the molecule for BaI: synthesis and crystal structures of [BaI22-OH2)2]3/∞, [BaI22-OH2)(OC3H6)]2/∞, [BaI2(thf)3]1/∞, and [BaI2(thf)5] · THF
K. M. Fromm, Angew. Chem. 1998, 109(24), 2876-2878; Angew. Chem. Int. Ed. Engl.199836(24), 2799-2801.  DOI: 10.1002/anie.199727991 

Organometallic tantalum complexes with phosphine, phosphanido and phosphinidene ligands. Syntheses and crystal structures of [Cp′TaCl4[PH2(2, 4, 6-Pri3C6H2)]], [Cp′Ta(μ-PPh2)(PPh2)]2·C7H8 and [Cp′TaCl[μ-P(2, 4, 6-Pri3C6H2)]]2· C7H8(Cp′ =C5H4Me)
G. A. Abdul Hadi, K. M. Fromm, S. Blaurock, S. Jelonek, E. Hey-Hawkins,  Polyhedron 199716(4), 721-731.  DOI: 10.1016/0277-5387(96)00269-0 

Reducible nanoscale molecular rods based on diacetylene-linked poly(phenylthio)-substituted benzenes
M. Mayor, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl. 199736(21), 2370-2372. DOI: 10.1002/anie.199723701 


Zintl anions as starting compounds for the synthesis of polynuclear transition metal complexes
R. Ahlrichs, D. Fenske, K. M. Fromm, H. Krautscheid, U. Krautscheid, O. Treutler, Chem. Eur. J. 1996, 2(2), 238-244.  DOI: 10.1002/chem.19960020217 


Mixed-valence dinuclear molybdenum complexes: synthesis and molecular structure of (Cp°Mo)2(μ-Cl)n(μ-PPh2)3-n (n=1, 0; Cp° = η5-C5Me4Et)
E. Hey-HawkinsK. M. Fromm, Polyhedron 199514(15/16), 2027-2035.  DOI:10.1016/0277-5387(95)00040-Y 

Synthesis and molecular structures of molybdenum complexes with phosphido, diphosphanyland diphosphene ligands 
E. Hey-HawkinsK. M. Fromm, Polyhedron 199514(20/21), 2825-2834.  DOI:10.1016/0277-5387(95)00220-M 

Synthesis and molecular structures of the molybdenum(II) complexes MoCl2(PMe3)2 and [Mo(μ-PPh2)(PPh2)(PMe3)]2
K. M. Fromm,  M. Plaikner, E. Hey-Hawkins, Z. Naturforsch. 199550(6), 894-898.  DOI: 10.1515/znb-1995-0610  Open Access


Reaction of cyclopentadienyl substituted molybdenum (V) tetrachlorides with LiPH(2,4,6-But3C6H2) and KPPh2(dioxane)2. Crystal structures of [Cp0Mo(μ-Cl)2]2 and [CpMo2(μ-Cl)3(μ-PPh2)] (Cp0 = C5Me4Et)
K. M. Fromm, E. Hey-Hawkins, Z. anorg. allg. Chem. 1993619(2), 261-270.  DOI: 10.1002/zaac.19936190207 


Synthesis and crystal structure of meso-(1,2,3-tricyclohexyltriphosphine-1,3-diyl)zirconocene (IV), [cyclic] Cp2Zr(PCy-PCy-PCy) (Cp =  η5-C5H5 ; Cy = C6H11)
K. M. Fromm, G. Baum, E. Hey-Hawkins, Z. anorg. allg. Chem. 1992615, 35-38.  DOI: 10.1002/zaac.19926150907