2018

A Concept for stimulated proton transfer in 1-(phenyldiazenyl)naphtalen-2ols
S. Hristova, V. Deneva, M. Pittelkow, A. Crochet, F. S. Kamounah, K. M. Fromm, P. E. Hansen, L. Antonov, Dyes and Pigments  2018, 156, 91-99.  DOI: 10.1016/j.dyepig.2018.03.070

Versatile synthesis of chiral 6-​oxoverdazyl radical ligands – new building blocks for multifunctional molecule-​based magnets
A. B. Solea, T. Wohlhauser, P. Abbasi, Y. Mongbanziama, A. Crochet, K. M. Fromm, G. Novitchi, C. Train, M. Pilkington, O. Mamula,  Dalton Trans.  2018, 47, 4785-4789.  DOI: 10.1039/C8DT00840J

Ag Nanoencapsulation for Antimicrobial Applications
S.-L. Abram, J. Gagnon, M. Priebe, N. Hérault, K. M. Fromm, Chimia  2018, Accepted.

Puckering behavior in six new phosphoric triamides containing aliphatic six- and seven-membered ring groups and a database survey of analogous ring-containing structures
B. V. Alviri, M. Pourayoubi, A. Saneei, M. Keikha, A. van der Lee. A. Crochet, A. Ajees, M. Nečas, K. M. Fromm, K. Damodaran, T. A. Jenny,  Tetrahedron  2018, 74, 1, 28-41.  DOI: 10.1016/j.tet.2017.11.030

Threading Salen-type Cu- and Ni-Complexes into One-Dimensional Coordination Polymers: Solution versus Solid State and the Size Effect of the Alkali Metal Ion
A. Finelli, N. Hérault, A. Crochet,  K. M. Fromm, Cryst. Growth Des.  2018, 2, 1215-1226.  DOI: 10.1021/acs.cgd.7b01769

WRI1 and DGAT1 regulate tocochromanol metabolism in arabidopsis
S. Pellaud, A. Bory, V. Chabert, J. Romanens, L. Chaisse-Leal, A. V. Doan, L. Frey, A. Gust, K. M. Fromm, L. Mène-Saffrané, New Phytologist  2018217, 245–260.  DOI: 10.1111/nph.14856

2017

Cis- and Trans-9,10-di(1H-imidazol-1-yl)-anthracene based coordination polymers of ZnII and CdII: synthesis, crystal structures and luminescence properties
S. I. Vasylevskyi, K. Regeta, A. Ruggi, S. Petoud, C. Piguet, and K. M. Fromm, Dalton Trans., 2018,47, 596-607.  DOI: 10.1039/C7DT03758A

The synergistic cooperation of NH⋯O and CH⋯O hydrogen bonds in the structures of three new phosphoric triamides
A. Saneei, M. Pourayoubi, J. P. Jasinski, T. A. Jenny, A. Crochet, K. M. Fromm & A. C. Keeley, Phosphorus, Sulfur, and Silicon and the Related Elementsaccepted. DOI: 10.1080/10426507.2017.1399128

Characteristics and properties of nano-LiCoO2 synthesized by pre-organized single source precursors: Li-ion diffusivity, electrochemistry and biological assessment
J.-P. Brog, A. Crochet, J. Seydoux, M. J. D. Clift, B. Baichette, S. Maharajan, H. Barosova, P. Brodard, M. Spodaryk, A. Züttel, B. Rothen-Rutishauser,  N.-H. Kwon, K. M. Fromm, JNanobiotechnol 2017, 15, 58. DOI: 10.1186/s12951-017-0292-3

Influence of the Sacrificial Polystyrene Removal Pathway on the TiO2 Nanocapsule Structure
N. Herault,  K. M. Fromm, Helvetica Chimica Acta 2017, 100(6), e1700014 . DOI: 10.1002/hlca.201700014

Different molecular assemblies in two new phosphoric triamides with the same C(O)​NHP(O)​(NH)2 skeleton: crystallographic study and Hirshfeld surface analysis
A. Saneei, M. Pourayoubi, T. A. Jenny, A. Crochet, K. M. Fromm, E. S. Shchegravina, Chemical papers 2017, 17, 1809. DOI: 10.1007/s11696-017-0168-x

Influence of anions and solvent molecules on the packing and emission spectra of coordination polymers based on silver ions and an anthracene derivative
J. Chen, N. Voutier, J. Rajabi, A. Crochet, D. M. Bassani, K. M. Fromm, CrysEngComm 2017, 19, 5106-5113. DOI: 10.1039/C7CE00846E

Model peptide studies of Ag+ binding sites from the silver resistance protein SilE
V. Chabert, M. Hologne, O. Sénèque, A. Crochet, O. Walker, K. M. Fromm, Chem. Commun. 2017, 53, 6105–6108. DOI: 10.1039/c7cc02630g

Quantitative Nano-characterization of Polymers Using Atomic Force Microscopy
M. Radiom, S. Kozhuharov, P. Kong, M. di Giannantonio,M. Ayer, P. Maroni, A. F. M. Kilbinger, K. M. Fromm, C. Weder, M. Borkovec, Chimia 201771(4), 195-198. DOI: 10.2533/chimia.2017.195

Formation of silver nanoparticles by electron transfer in peptides and c-cytochromes
S. I. Vasylevskyi, S. Kracht, P. Corcosa, K. M. Fromm, B. Giese, M. Füeg, Angew. Chem. Int. Ed. 2017, 56, 5926 –5930. DOI: 10.1002/anie.201702621

Heptacoordinate Co(II) complex: a new architecture for photochemical hydrogen production
F. Lucarini, M. Pastore, S. I. Vasylevskyi, M. Varisco, E. Solari, A. Crochet, K. M. Fromm, F. Zobi, A. Ruggi, Chem. Eur. J. 2017, 23, 6768-6771, DOI: 10.1002/chem.201701427

Embedding CeO2 nanocontainers in a TiO2 coating on glass surfaces
J. Gagnon, R. A. Caruso, and K. M. Fromm, AIMS Bioengineering 2017,  4(1), 171-178. DOI: 10.3934/bioeng.2017.1.171

Antimicrobial silver-filled silica nanorattles with low immunotoxicity in dendritic cells
M. Priebe, J. Widmer, N. Suhartha Löwa, S.-L. Abram, I. Mottas, A.-K. Woischnig, P. S. Brunetto, N. Khanna, C. Bourquin, K. M. Fromm, Nanomedicine: NBM 2017, 13(1), 11-22. DOI: 10.1016/j.nano.2016.08.002

Nanoparticle shapes of LiMnPO4, Li+-diffusion orientation and diffusion coefficients for high volumetric energy Li+-ion cathodes
N.-H. Kwon, H. Yin, T. Vavrova, J. H.-W. Lim, U. Steiner, B. Grobéty, K. M. Fromm, J. Power Sources 2017, 342, 231-240. DOI: 10.1016/j.jpowsour.2016.11.111

2016

Going nano for batteries and drug delivery
S.-L. Abram, J.-P. Brog, P. S. Brunetto, A. Crochet, J. Gagnon, N.-H. Kwon, S. Maharajan, M. Priebe, K. M. Fromm, Chimia 2016, 70(9), 661. DOI:10.2533/chimia.2016.661 

Tandem ring-opening-ring-closing metathesis for functional metathesis catalysts
A. A. Nagarkar, M. Yasir, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Angew. Chem., Int. Ed. 2016, 55, 12343-12346. DOI: 10.1021/ja4039278

Crystal structures of a copper(II) and the isotypic nickel(II) and palladium(II) complexes of the ligand (E)-1-[(2,4,6-tri­bromo­phen­yl)diazen­yl]naphthalen-2-ol
S. Chetioui, D.-A. Rouag, J.-P. Djukic, C. G. Bochet, R. Touzani, C. Bailly, A. Crochet and K. M. Fromm, Acta Cryst. 2016, 72(8), 1093-1098. DOI:10.1107/S205698901601080X

Synthesis of new polyether ether ketone derivatives with silver binding site and coordination compounds of their monomers with different silver salts
J. Girard, N. Joset, A. Crochet, M. Tan, A. Holzheu, P. S. Brunetto, K. M. Fromm, Polymers 2016, 8(6), 208. DOI:10.3390/polym8060208

Synthesis, characterization, antibacterial activity and cytotoxicity of hollow TiO2-coated CeO2 nanocontainers encapsulating silver nanoparticles for controlled silver release

Mixed metal multinuclear Cr(III) cage compounds and coordination polymers based on unsubstituted phenolate: design, synthesis, mechanism and properties
A. Crochet, J.-P. Brog, K. M. Fromm, Cryst. Growth Des201616(1), 189-199. DOI: 10.1021/acs.cgd.5b01084

A thermo- and mechanoresponsive cyano-substituted oligo(p-phenylene vinylene) derivative with five emissive states
Y. Sagara, A. Lavrenova, A. Crochet, Y. C. Simon, K. M. Fromm, C. Weder, Chem. Eur. J. 2016 22(13), 4374–4378. DOI: 10.1002/chem.201600272

Preventing implant-associated infections by silver coating
R. Kuehl, P. S. Brunetto, A.-K. Woischnig, M. Varisco, Z. Rajacic, J. Vosbeck, L. Terracciano, K. M. Fromm, N. Khanna, Antimicrob. Agents Chemother. 2016, 60(4), 2467-2475. DOI: 10.1128/AAC.02934-15

The first phosphoramide–mercury(II) complex with a Cl2 Hg–OP[N(C)(C)]3 segment
A. Saneei, M. Pourayoubi, A. Crochet, K. M. Fromm, Acta Crystallogr. C. Struct. Chem201672(3), 230-233. DOI: 10.1107/S2053229616002394

2015

Synthesis, X-ray structure and DFT calculation of oxido-vanadium(V) complex with a tridentate Schiff base ligand
I. Sheikhshoaie, S. Y. Ebrahimipour, A. Crochet, K. M. Fromm, Res. Chem. Intermed2015, 41(4), 1881-1891. DOI 10.1007/s11164-013-1317-7

Nanorattles or yolk-shell nanoparticles-What are they, How are they made, and What are they good for?
M. Priebe, K. M. Fromm, Chem. Eur. J2015, 21(10), 3854-3874. DOI:10.1002/chem.201405285

Electron transfer in peptides: on the formation of silver nanoparticles
S. Kracht, M. Messerer, M. Lang, S. Eckhardt, M. Lauz, B. Grobety, K. M. Fromm, B. Giese, Angew. Chem. Int. Ed201554(10), 2912-2916.  DOI: 10.1002/anie.201410618

Controlled tautomeric switching in azonaphthols tuned by substituents on the phenyl ring
L. Antonov, V. DenevaS. SimeonovV. KurtevaA. CrochetK. M. FrommB. ShivachevR. NikolovaM. SavareseC. Adamo, ChemPhysChem, 201516(3), 649-657. DOI: 10.1002/cphc.201402691

cis-Dioxido-molybdenum(VI) complexes of tridentate ONO hydrazone Schiff base: synthesis, characterization, X-ray crystal structure, DFT calculation and catalytic activity
S. Y. Ebrahimipour, H. Khabazadeh, J. Castro, I. Sheikhshoaie, A. Crochet, K. M. Fromm, Inorg. Chem. Acta 2015, 427, 52-61. Doi:10.1016/j.ica.2014.11.023

4-Hydroxy-1-naphthaldehydes: proton transfer or deprotonation
Y. Manolova, V. Kurteva, L. Antonov, H. Marciniak, S. Lochbrunner, A. Crochet, K. M. Fromm, F. S. Kamounah, P. E. Hansen, Phys. Chem. Chem. Phys. 201517(15), 10238-10249. DOI: 10.1039/C5CP00870K

Toxicity and protective effects of cerium oxide nanoparticles (nanoceria) depending on their preparation method, particle size, cell type, and exposure route
J. Gagnon, K. M. Fromm, Eur. J. Inorg. Chem201527, 4510-4517. DOI: 10.1002/ejic.201500643

Towards cardiolite-inspired carbon monoxide releasing molecules – reactivity of d4, d5 rhenium and dmanganese carbonyl complexes with isocyanide ligands
E. Kottelat, V. Chabert, A. Crochet, K. M. Fromm, F. Zobi, Eur. J. Inorg. Chem201534, 5628-5638. DOI: 10.1002/ejic.201500756

Layer-by-layer grown scalable redox-active ruthenium-based molecular multilayer thin films for electrochemical applications and beyond
V. Kaliginedi, H. Ozawa, A. Kuzume, S. Maharajan, I. V. Pobelov, N.-H. Kwon, M. Mohos, P. Broekmann, K. M. Fromm, M.-A. Haga, T. Wandlowski, Nanoscale 2015, 7(42), 17685–17692. DOI: 10.1039/c5nr04087f

Nanomaterials meet Li-ion batteries
N.-H. Kwon, J.-P. Brog, S. Maharajan, A. Crochet, K. M. Fromm, Chimia 201569(12), 734-736. DOI: 10.2533/chimia.2015.734

Construction of polynuclear lanthanide (Ln = DyIII, TbIII, and NdIII) cage complexes using pyridine–pyrazole-based ligands: versatile molecular topologies and SMM behavior
S. Bala, M. S. Bishwas, B. Pramanik, S. Khanra, K. M. Fromm, P. Poddar, R. Mondal, Inorg. Chem. 2015, 54 (17), 8197–8206. DOI: 10.1021/acs.inorgchem.5b00334

Integrating silver compounds and nanoparticles into ceria nanocontainers for antimicrobial applications
J. Gagnon, M. J. D. Clift, D. Vanhecke, D. A. Kuhn, P. Weber, A. Petri-Fink, B. Rothen-Rutishauser, K. M. Fromm, J. Mat. Chem. B 2015, 3(9), 1760-1768. DOI: 10.1039/C4TB02079K

2014

Investigation on the growth and characterization of novel creatinium malate single crystal
S. Mathuri, M. Kayalvizhi, G. Vasuki, R. Ramesh Babu, K. Ramamurthi, A. Crochet, K. M. Fromm, Chem. Sci. Rev. Lett. 2014, 3(12), 1208-1218. ISSN 2278-6783

One-pot synthesis and catalytic properties of encapsulated silver nanoparticles in silica nanocontainers
M. Priebe, K. M. Fromm, Particles and Particle Systems Characterization 2014, 31(6), 645-651. DOI: 10.1002/ppsc.201300304

New antimicrobial and biocompatible implant coating with synergic silver–vancomycin conjugate action
M. Varisco, N. Khanna, P. S. Brunetto, K. M. Fromm, ChemMedChem. 2014, 9(6), 1221-1230.  DOI: 10.1002/cmdc.201400072

Impact of composite structure and morphology on electronic and ionic conductivity of carbon contained LiCoO2 cathode
N.-H. Kwon, H. Yin, P. Brodard, C. Sugnaux, K. M. Fromm, Electrochim. Acta 2014134, 215-221. DOI:10.1016/j.electacta.2014.04.121

Synthesis, crystal structure and antimicrobial activities of di ((E)-2-(pyridine-2-ylmethylene)hydrazinecarboxamide) cobalt(II) dichloride trihydrate
J. Novina, G. Vasuki, M. Suresh, M. S. A. Padusha, K. M. Fromm, A. Crochet, Phys. Science Inter. J. 20144, 816-824. DOI: 10.9734/PSIJ/2014/7803

A new mixed-ligand copper(II) complex of (E)-N’-(2-hydroxybenzylidene)acetohydrazide: synthesis, characterization, NLO behavior, DFT calculation and biological activities
S. Y. Ebrahimipour, I. Sheikhshoaie, A. Crochet, M. Khaleghi, K. M. Fromm, J. Mol. Struct. 20141072, 267-276. DOI:10.1016/j.molstruc.2014.05.024

2013

pH-Dependent coordination of AgI ions by histidine: experiment, theory, and a model for SilE
L. Mirolo, T. Schmidt, S. Eckhardt, M. Meuwly, K. M. Fromm, Chem. Eur. J. 201319(5), 1754-1761.  DOI: 10.1002/chem.201201844

7-[(Morpholin-4-yl)(phenyl)methyl]quinolin-8-ol
J. J. Novina, G. Vasuki, C. Muthukumar, A. Sabastiyan, A. Crochet, K. M. Fromm, Acta Cryst. 201369(1), o45. DOI:10.1107/S1600536812049343

Ethyl 5-methoxy-2-trifluoromethyl-1H-indol-3-carboxyl-ate
A. Crochet, I. Alimi, C. G. Bochet, K. M. Fromm, Acta Cryst. 201369(3), o339. DOI:10.1107/S1600536813002614

Barium bright and heavy
K. M. Fromm, Nature Chem. 20135(2), 146. DOI:10.1038/nchem.1551

Ring a bell: disubstituted calix[4]arene as ligand for transition metal chlorides
A. Crochet, K. M. Fromm, Polyhedron 201352, 610-616. DOI:10.1016/j.poly.2012.08.004

Rings, chains and helices: new antimicrobial silver coordination compounds with (iso-)nicotinic acid derivatives
I. Chevrier, J. L. Sagué, P. S. Brunetto, N. Khanna, Z. Rajacic, K. M. Fromm, Dalton Trans. 2013, 42(1), 217-231. DOI: 10.1039/C2DT31259J

Kinetics of ion transport through supramolecular channels in single crystals
C. D. Assouma, A. Crochet, Y. Chérémond, B. Giese, K. M. Fromm, Angew. Chem. Int. Ed. 2013, 52(17), 4682-4685. DOI: 10.1002/anie.201208195

CFA-2 and CFA-3 (coordination framework Augsburg University-2 and -3); novel MOFs assembled from trinuclear Cu(I)/Ag(I) secondary building units and 3,3’,5,5’-tetraphenyl-bipyrazolate ligands
M. Grzywa, C. Gessner, D. Denysenko, B. Bredenkötter, F. Gschwind, K. M. Fromm, W. Nitek, E. Klemm, D. Volkmer, Dalton Trans. 201342(19), 6909-6921.  DOI: 10.1039/C3DT32302A

Development of a polystyrene sulfonate/silver nanocomposite with self-healing properties for biomaterial applications
J. Girard, P. S. Brunetto, O. Braissant, Z. Rajacic, N. Khanna, R. Landmann, A. U. Daniels, K. M. Fromm, C. R. Chim. 201316(6), 550-556. DOI:10.1016/j.crci.2013.04.010

Silver coordination polymers with isonicotinic acid derived short polyethylene gylcol – Synthesis, structures, anion effect and solution behavior
K. M. Fromm, J. L. Sagué, A. Y. Robin, Inorg. Chim. Acta 2013403, 2-8.  DOI:10.1016/j.ica.2012.12.021

A family of immobilizable chiral bis(pinenebipyridine) ligands
A. Pöllnitz, R. Skupienski, H. Stoeckli-Evans, A. Crochet, A. Silvestru, K. M. Fromm, O. Mamula, Synlett 201324(19), 2555-2558.  DOI: 10.1055/s-0033-1339847

Bioinorganic chemistry of silver: its interactions with amino acids and peptides
K. M. Fromm, Chimia 201367(12), 851-854. DOI:10.2533/chimia.2013.851

Controlled tautomerism – switching caused by an “underground” anionic effect
L. Antonov, V. Deneva, V. Kurteva, D. Nedeltcheva, A. Crochet, K. M. Fromm, RSC Advances 20133(47), 25410-25416. DOI: 10.1039/C3RA45326J

Polymorphism, what it is and how to identify it: a systematic review

J.-P. Brog, C.-L- Chanez, A. Crochet, K. M. Fromm, RSC Advances 2013, 3(38), 16905-16931.  DOI: 10.1039/C3RA41559G

2012

Tautomerism in 1-phenylazo-4-naphthols: experimental results vs. quantum-chemical predictions
L. Antonov, V. Kurteva, A. Crochet, L. Mirolo, K. M. Fromm, S. Angelova, Dyes and Pigments 201292(1), 714-723. DOI:10.1016/j.dyepig.2011.06.026

Switching azonaphthols containing a side chain with limited flexibility. Part 1. Synthesis and tautomeric properties
V. B. Kurteva, L. M. Antonov , D. V. Nedeltcheva, A. Crochet, K. M. Fromm, R. P. Nikolova, B. L. Shivachev, M. S. Nikiforova, Dyes and Pigments 201292(3), 1266-1277. DOI:10.1016/j.dyepig.2011.07.013

Synthesis and characterization of new pentacoordinate iron based aryloxide complexes
Y. Chérémond, A. Crochet, K. M. Fromm, Eur. J. Inorg. Chem. 2012, 2012(16), 2725-2730. DOI: 10.1002/ejic.201101054

Effect of increasing ligand length on the structure of silver complexes
F. Gschwind, K. M. Fromm, CrystEngComm 201214(11), 4008-4015. DOI: 10.1039/C2CE25110H

A transparent, flexible, ion conductive, and luminescent PMMA ionogel based on a Pt/Eu bimetallic complex and the ionic liquid [Bmim][N(Tf)2]
Z.-L. Xie, H.-B. Xu, A. Gessner, M. U. Kumke, M. Priebe, K. M. Fromm, A. Taubert, J. Mat. Chem. 201222(16), 8110-8116.  DOI: 10.1039/C2JM15862K

Enhanced electrochemical performance of < 30 nm thin LiMnPO4 nanorods with a reduced amount of carbon as a cathode for lithium ion batteries
N. H. Kwon, K. M. Fromm, Electrochim. Acta 201269, 38-44. DOI:10.1016/j.electacta.2012.02.040

Single crystal to single crystal polymorphic phase transition of a silver nitrate 24-crown-8 complex and its pseudo-polymorphism
J. Girard, K. M. Fromm, CrystEngComm 201214(20), 6487-6491. DOI: 10.1039/C2CE25875G

The influence of dipole moments on the mechanism of electron transfer through helical peptides
M. Lauz, S. Eckhardt, K. M. Fromm, B. Giese, PhysChemChemPhys 201214(40), 13785-13788. DOI: 10.1039/C2CP41159H

A comparative study of (poly)ether adducts of alkaline earth iodides ­ an overview including new compounds
W. Maudez, K. M. Fromm, Z. Anorg. Allg. Chem. 2012638(11), 1810-1819. DOI: 10.1002/zaac.201200231

Antibacterial properties of nanoparticles
M. J. Hajipour, K. M. Fromm, A. Akbar Ashkarran, D. Jimenez de Aberasturi, I. R. de Larramendi, T. Rojo,  V. Serpooshan, W. J. Parak, M. Mahmoudi, Trends Biotechnol. 201230(10), 499-511. DOI:10.1016/j.tibtech.2012.06.004

Efficient amine end-functionalization of living ring-opening metathesis polymers
A. A. Nagarkar, A. Crochet, K. M. Fromm, A. F. M. Kilbinger, Macromolecules 2012, 45(11), 4447-4453. DOI: 10.1021/ma300602p

Preparation of imidazolidin-4-ones and their evaluation as hydrolytically cleavable precursors for the slow release of bioactive volatile carbonyl derivatives
A. Trachsel, B. Buchs, G. Godin, A. Crochet, K. M. Fromm, A. Herrmann, Eur. J. Org. Chem. 201214, 2837-2854. DOI: 10.1002/ejoc.201200081

2011

Give silver a shine
K. M. Fromm, Nature Chemistry 20113(2), 178. DOI:10.1038/nchem.970

Electron transfer in peptides: the influence of charged amino acids
J. Gao, P. Müller, M. Wang, S. Eckhardt, M. Lauz, K. M. Fromm, B. Giese, Angew. Chem., Int. Ed. 2011, 50(8), 1926-1930.  DOI10.1002/anie.201003389

In vitro biocompatibility of new silver(I) coordination compound coated-surfaces for dental implant applications
P. S. Brunetto, T. Vig Slenters, K. M. Fromm, Materials 20114, 355-367. DOI:10.3390/ma4020355

Polymorph of dibenzo-24-crown-8 and its mercury complex
A. Crochet, E. Kottelat, A. Fleury, M. Neuburger, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(6), 672-675. DOI: 10.1002/zaac.201100065

(E)-1-(4-Methoxyanthracen-1-yl)-2-phenyldiazene
A. Crochet, K. M. Fromm, V. Kurteva, L. Antonov, Acta Cryst E, Struct Reports Online 2011E67(4), o993.  ISSN 1600-5368

Tetraethylene glycol adducts of alkaline earth halides
F. Gschwind, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(12), 1871-1879.  DOI: 10.1002/zaac.201100192

Coordination networks of mercury(II) halides and polyether ligand
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2011637(14-15), 2089-2092.  DOI: 10.1002/zaac.201100283

Nanoencapsulation of anti-microbial drugs
J. Gagnon, P. Weber, K. M. Fromm, Europ. Cells & Materials 201121(2), 49. ISSN 1473-2262

2010

From alkaline earth ion aggregates via transition metal coordination polymer networks towards heterometallic single source precursors for oxidic materials
F. Gschwind, A. Crochet. W. Maudez, K. M. Fromm, Chimia 201064(5), 299-302. DOI: 10.2533/chimia.2010.299

Polyether adducts of d-block metal compounds as starting materials for new cluster compounds
A. Crochet, K. M. Fromm, Z. Anorg. Allg. Chem. 2010636(8), 1484-1496. DOI: 10.1002/zaac.201000022

Of chains and rings: synthetic strategies and theoretical investigations for tuning the structure of silver coordination compounds and their applications
T. Vig Slenters, J. L. Sagué, P. S. Brunetto, S. Zuber, A. Fleury, L. Mirolo, A. Y. Robin, M. Meuwly, O. Gordon, R. Landmann, A. U. Daniels, and K. M. Fromm, Materials 20103(5), 3407-3429. DOI:10.3390/ma3053407

Tautocrowns: a concept for a sensing molecule with an active side-arm
L. M. Antonov, V. B. Kurteva, S. P. Simeonov,  V. V. Deneva, A. Crochet, K. M. Fromm, Tetrahedron 201066(24), 4292-4297.  DOI:10.1016/j.tet.2010.04.049

Silver coordination polymers for prevention of implant infection: thiol interaction, impact on respiratory chain enzymes, and hydroxyl radical induction
O. Gordon, T. Vig. Slenters, P. S. Brunetto, A. E. Villaruz, D. E. Sturdevant, M. Otto, R. Landmann, K. M. Fromm, Antimicrob. Agents Chemother. 201054(10), 4208-4218.  DOI: 10.1128/AAC.01830-09

Synthesis, X-ray crystal structure, thermal and solution studies of a centrosymmetric metal-organic polymer based on proton transfer methodology
H. Eshtiagh-Hosseini, A. Hassanpoor, N. Alfi, M. Mirzaei, K. M. Fromm, A. Shokrollahi, F. Gschwind, E. Karami, J. Coord. Chem. 201063(18), 3175-3186.  DOI: 10.1080/00958972.2010.508518

Excimer formation in crystalline and nanostructured coordination polymers
J. Chen, A. Neels, K. M. Fromm, Chem. Commun. 2010, 46(43), 8282-8284.  DOI: 10.1039/C0CC03011B

On the chemical synthesis of titanium nanoparticles from ionic liquids
A. A. Ayi, V. Khare, P. Strauch, J. Girard, K. M. Fromm, A. Taubert, Monatshefte für Chemie 2010141(12), 1273-1278.  DOI: 10.1007/s00706-010-0403-4

A new three dimensional proton transfer compound including citric acid and 2,4,6-triamine-1,3,5-triazine: synthesis, characterization and X-ray crystal structure
H. Eshtiagh‐Hosseini, M. Mahjoobizadeh, M. Mirzaei, K. M. Fromm, A. Crochet, Eur. J. Chem. 2010, 1(3), 179-181. DOI:10.5155/eurjchem.1.3.179‐181.44

Coordination polymer networks: an alternative to classical polymers?
K. M. Fromm, J. L. Sagué, L. Mirolo, Macromol. Symp. 2010, 291–292, 75–83. DOI: 10.1002/masy.201050509

2009

Silver-nanoparticle formation in different sizes induced by peptides identified within split-and-mix libraries
K. Belser, T. Vig Slenters, C. Pfumbidzai, G. Upert, L. Mirolo, K. M. Fromm, H. Wennemers, Angew. Chem. Int. Ed. 2009, 48(20), 3661-3664. DOI: 10.1002/anie.200806265

 

The heterometallic clusters of trivalent rare earth metals of [Ln(OPh)6{Li(dme)}3] with Ln = Eu and Sm
W. Maudez, K. M. Fromm, Helv. Chim. Acta 2009, 92(11), 2349-2356. DOI: 10.1002/hlca.200900171

Solid state tautomerism in 2-((phenylimino)methyl)naphthalene-1-ol
D. Nedeltcheva, F. S. Kamounah, S. Fadhil, L. Mirolo, K. M. Fromm, L. Antonov, Dyes and Pigments 200983(1), 121-126.  DOI:10.1016/j.dyepig.2009.04.002

Multitopic ligand design: a concept for single-source precursors
F. Gschwind, O. Sereda, K. M. Fromm, Inorg. Chem. 200948(22), 10535-10547. DOI: 10.1021/ic9009064

Getting hooked on supramolecular coordination chemistry
K. M. Fromm, Chimia 2009,  63(12), 858-859. DOI:10.2533/chimia.2009.858

2008

Antimicrobial coatings for implant surfaces
P. S. Brunetto, K. M. Fromm, Chimia 200862(4), 249-252. DOI:10.2533/chimia.2008.249

Silver nanoparticle engineering via oligovaline organogels
A. Mantion, A. G. Guex, A. Foelske, L. Mirolo, K. M. Fromm, M. Painsi, A. Taubert, Soft Matter 20084(3), 606-617.  DOI: 10.1039/B712826F

Amino acids in iron oxide mineralization: (incomplete) crystal phase selection is achieved even with single amino acids
A. Mantion, F. Gozzo, B. Schmitt, W. B. Stern, Y. Gerber, A. Y. Robin, K. M. Fromm, M. Painsi, A. Taubert, J. Phys. Chem. C 2008112(32), 12104-12110. DOI: 10.1021/jp075449u

Silver coordination compounds as light-stable, nano-structured and anti-bacterial coatings for dental implant and restorative materials
T. Vig Slenters, I. Hauser-Gerspach, A. U. Daniels, K. M. Fromm, J. Mat. Chem. 200818(44), 5359–5362. DOI: 10.1039/B813026D

Counterion effect on the formation of coordination polymer networks between AgNO3 and L (2,2′-oxybis(ethane-2,1-diyl) diisonicotinate). Part 2
J. L. Sagué, M. Meuwly, K. M. Fromm, CrystEngComm 200810(11), 1542-1549.  DOI: 10.1039/B803158D

Combating implant infections. Remarks by a women’s team
C. R. Arciola, N. Balaban, L. Baldassarri, K. Fromm, G. M. Hansch, U. Obst, E. Presterl, S. Stefani, J. Verran, L. Visai, The International journal of artificial organs 200831(9), 858-864.  ISSN:0391-3988

2007

Structure–property relationships: Polymorphism, solvates, and clay behavior in the one-dimensional coordination polymer chains [Ag(L)(NO3)](H2O)n, L = ethanediyl bis(isonicotinate), n= 0, and 2
A. Y. Robin, J. L. Sague Doimeadios, A. Neels, T. Vig Slenters,  K. M. Fromm, Inorg. Chim. Acta 2007, 360(1), 212-220.  DOI:10.1016/j.ica.2006.07.086


Analogy of the coordination chemistry of alkaline earth metal and lanthanide Ln2+ ions: the isostructural zoo of mixed metal cages [IM(OtBu)4{Li(thf)}4(OH)] (M=Ca, Sr, Ba, Eu), [MM’6(OPh)8(thf)6] (M=Ca, Sr, Ba, Sm, Eu, M’=Li, Na), and their derivatives with 1,2-dimethoxyethane
W. Maudez, M. Meuwly, K. M. Fromm, Chem. Eur. J. 200713(29), 8302 – 8316.  DOI: 10.1002/chem.200700597

From simple rings to one-dimensional channels with calix[8]arenes, water clusters and alkali metal ions

R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Tetrahedron 2007, 63(44), 10751-10757.  DOI:10.1016/j.tet.2007.07.048


Transport properties of solid state crown ether channel systems
K. M. Fromm, R. D. Bergougnant, Solid State Sciences 20079(7), 580-587. DOI:10.1016/j.solidstatesciences.2007.04.012

2006

Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies
M. Dulak, R. Bergougnant, K. M. Fromm, H. R. Hagemann, A. Y. Robin, T. A. Wesolowski, Spectrochim. Acta Mol. Biomol. Spectrosc. 2006, 64A(2), 532–548. DOI:10.1016/j.saa.2005.07.060

[Ag(isonicotinamide)2NO3]2– a stable form of silver nitrate
T. Dorn, K. M. Fromm, C. Janiak, Aust. J. Chem. 200659(1), 22-25.  DOI: 10.1071/CH05270

On the coordination behaviour of NO3 in coordination compounds with Ag+Part 1. Solubility effect on the formation of coordination polymer networks between AgNO3 and L(L = ethanediylbis(isonicotinate) as a function of solvent
A. Y. Robin, J. L. Sagué, K. M. Fromm, CrystEngComm. 20068, 403–416.  DOI: 10.1039/B517191A

Di-Benzo-18-crown-6 and its derivatives as ligands in the search for ion channels
K. M. Fromm, R. D. Bergougnant, A. Y. Robin, Z. Anorg. Allg. Chem. 2006632(5), 828-836. DOI: 10.1002/zaac.200500470

Substitution reactions on alkaline earth metal iodides: a large anionic Sr12-aggregate [{Sr6(O)(μ3-I)(I)2(OtBu)7(thf)3}2(μ-I)]
W. Maudez, T. Vig-Slenters, L. Mirolo, A. Fleury, K. M. Fromm, Main Group Chemistry 20065(1), 41-49.  DOI: 10.1080/10241220600841862

Substitution reactions on CaI2: synthesis of mixed metal lithium-calcium-phenolates, and cluster transformation as a function of solvent
W. Maudez, D. Häussinger, K. M. Fromm, Z. Anorg. Allg. Chem. 2006, 632(14), 2295-2298. DOI: 10.1002/zaac.200600170

Film-forming polymers containing in the main-chain dibenzo crown ethers with aliphatic (C10-C16), aliphatic-aromatic, or oxyindole spacers
M. G. Zolotukhin, M.C. G. Hernández, A. M. Lopez, L. FominaG. Cedillo, A. Nogales, T. Ezquerra, D. RuedaH. M. Colquhoun, K. M. Fromm, A. Ruiz-Treviño, M. Ree, Macromolecules 2006, 39(14), 4696-4703. DOI: 10.1021/ma052148e

The first two-dimensional polycatenane: a new type of robust network obtained by Ag-connected one-dimensional polycatenanes
J. L. Sagué, K. M. Fromm, Cryst. Growth Des. 2006, 6(7), 1566-1568.  DOI: 10.1021/cg060255+

A structural study of copper(II) carboxylates: crystal structure and physical characterisation of [Cu2(2-bromopropanoato)4(caffeine)2]
F. Valach, M. Melnik, G. Bernardinelli, K. M. Fromm, J. Chem. Cryst. 200636(9), 571-580.  DOI: 10.1007/s10870-006-9102-8

2005

Recent advances in the chemistry of “clusters” and coordination polymers of alkali, alkaline earth metal and group 11 compounds
K. M. Fromm, E. D. Gueneau, A. Y. Robin, W. Maudez, J. Sague, R. Bergougnant, Z. Anorg. Allg. Chem. 2005631(10), 1725-1740.  DOI: 10.1002/zaac.200500079

Chiral S-1,1’-bi-2-naphthol (S-BINOL) as a synthon for supramolecular hydrogen-bonded {(S-BINOLATn-)(S-BINOL)n}-strands with naphthyl-paneled cavities or channels for a Cd(NH3)4-fragment (n = 2) or [Ag(NH3)2]+ (n = 1). Part 2.
B. Paul, C. Näther, K. M. Fromm, C. Janiak, CrystEngComm. 20057(51), 309–319.  DOI: 10.1039/B502202A

“Hooked on” calix[8]arenes: a (H2O)10-cluster with an unprecedented structure
R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Cryst. Growth Des. 20055(5), 1691-1694.  DOI: 10.1021/cg050201k

Concomitant crystallization of two polymorphs – a ring and a helix: concentration effect on supramolecular polymorphism or isomerism
K. M. Fromm, J. L. Sagué Doimeadios, A. Y. Robin, Chem. Commun. 200536, 4548-4550.  DOI: 10.1039/B506389B

2004

1[M(μ-O2C-C6H4-CO2)(NH3)2] (M = Cu, Cd; O2C-C6H4-CO2 = benzene-1,4-dicarboxylate, terephthalate): 1D coordination polymers with strong inter-chain hydrogen bonding
B. Paul, B. Zimmermann, K. M. Fromm, C. Janiak, Z. Anorg. Allg. Chem. 2004, 630(11), 1650-1654.  DOI: 10.1002/zaac.200400240

Molecular paneling of rac-1,1’-bi-2-naphthol/~ate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4or 6]2+complexes (M = Ni, Zn, Cd) in cavities of {[BINOLAT]2-(BINOL)2}-strands
B. Paul, C. Näther, B. Walfort, K. M. Fromm, B. Zimmermann, H. Lang, C. Janiak, CrystEngComm 20046(51), 293-297.  DOI: 10.1039/B410933C

How many structures are there for {[AgL](NO3)(H2O)n}? Water-content dependent variations in the structure of {[AgL](NO3)(H2O)n}, n = 0, 1, 2; L = ethanediyl bis(isonicotinate)
A. Y. Robin, M. Meuwly, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 20046(60), 336–343. DOI: 10.1039/B413232G

2003

Synthesis and structural analysis of the polymetallated alkali calixarenes [M4(p-tert-butylcalix[4]arene-4H)(thf)x]2·n THF (M = Li, K; n = 1 or 6; x = 4 or 5) and [Li2(p-tert-butylcalix[4]arene-2H)(H2O)(μ-H2O)(thf)]·3THF
E. D. Gueneau, K. M. Fromm, H. Goesmann, Chem. Eur. J. 20039(2), 509-514. DOI: 10.1002/chem.200390053

“One-dimensional water” and “one-dimensional acid”: synthesis and the unique crystal structure of math image[(H2O)⊂(DB18C6)(μ2-H2O)2/2]math image[(H3O)⊂(DB18C6)(μ2-H2O)2/2]I3 (DB18C6 = dibenzo-18-crown-6)
K. M. Fromm, E. D. Gueneau, H. Goesmann, C. G. Bochet, Z. Anorg. Allg. Chem. 2003629(4), 597-600.  DOI: 10.1002/zaac.200390101

Understanding the formation of new clusters of alkali and alkaline earth metals: a new synthetic approach, single crystal structures and theoretical calculations
K. M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, H. Chermette, J. Am. Chem. Soc. 2003125(12), 3593-3604.  DOI: 10.1021/ja0205737


Oxygen donor stabilized alkaline earth metal iodides
K M. Fromm, Chimia 200357(4), 175-178.  CODEN:CHIMAD; ISSN:0009-4293

Polar molecular precursors for alkali and alkaline earth metal clusters and low-dimensional polymer structures: the solid state structures of [CaI(dme)3]I, and cis-[SrI2(diglyme)2] (dme = CH3OC2H4OCH3; diglyme = CH3(OC2H4)2OCH3)
K. M. Fromm, W. Maudez, Eur. J. Inorg. Chem. 200318, 3440-3444. DOI: 10.1002/ejic.200300241

Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)
A. Y. Robin, K. M. Fromm, H. Goesmann, G. Bernardinelli, CrystEngComm. 20035(71), 405–410.  DOI: 10.1039/B309410C

2002

Crown ethers as stabilizing ligands for asymmetric coordination: synthesis, crystal structure, and physical properties of [Na ⊂ (DB18C6)I(thf)], [Na ⊂ (DB18C6)I(1,3-dioxolane)], and [Na ⊂ (DB24C8)]I (DB18C6 = Dibenzo-18-crown-6, DB24C8 = Dibenzo-24-crown-8)
K. M. Fromm, E. D. Gueneau, J.-P. Rivera, G. Bernardinelli, H. Goesmann, Z. Anorg. Allg. Chem. 2002628(1), 171-178.  DOI: 10.1002/1521-3749(200201)628:1<171::AID-ZAAC171>3.0.CO;2-K

Ionic or covalent? Can some first hints be derived from the solid state structures of alkaline earth metal halide adducts?
K. M. Fromm, CrystEngComm. 20024(57), 318-322.  DOI: 10.1039/B201975M

Recent advances in the chemistry of clusters and inorganic polymers of alkali and alkaline earth metal compounds
K. M. Fromm, Chimia 200256(12), 676-680. CODEN:CHIMAD; ISSN:0009-4293

2001

Electron transfer through molecular bridges between reducible pentakis(thiophenyl)benzene subunits
M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Chem. Eur. J. 20017(6), 1266-1272.  DOI: 10.1002/1521-3765(20010316)7:6<1266::AID-CHEM1266>3.0.CO;2-S

Hydrogen-bonding and metal-ion mediated self-assembly of a nanoporous crystal lattice
D. G. Kurth, K. M. Fromm, J.-M. Lehn, Eur. J. Inorg. Chem. 2001, (6), 1523-1526.  DOI: 10.1002/1099-0682(200106)2001:6<1523::AID-EJIC1523>3.0.CO;2-2

A logical concept of structure prediction derived from supramolecular polymers of alkaline earth metal halides formed by hydrogen bonding and complexation of the metal ion
K. M. Fromm, Chem. Eur. J. 20017(10), 2236-2244.  DOI: 10.1002/1521-3765(20010518)7:10<2236::AID-CHEM2236>3.0.CO;2-S

Synthesis and crystal structure of the one-dimensional polymer compound 1{[Ba(OTf)2(thf)3]2[Ba(OTf)2(thf)2]}(OTf = CF3SO3) – excerpts from a three-dimensional structure as an access to new materials?
K. M. Fromm, G. Bernardinelli, Z. Anorg. Allg. Chem. 2001627(7), 1626-1630.  DOI: 10.1002/1521-3749(200107)627:7<1626::AID-ZAAC1626>3.0.CO;2-Q

2000

Similar coordination – different dimensionality: synthesis, single crystal structures and theoretical studies of  hydrogen-bonded {[Ca(H2O)2L4]I2}n/∞ (1: L = CH3COOC2H5; 2: L = OC4H8)
K. M. Fromm, G. Bernardinelli,  M.-J. Mayor-Lopez, J. Weber, H. Goesmann, Z. Anorg. Allg. Chem. 2000, 626(7), 1685-1691.  DOI: 10.1002/1521-3749(200007)626:7<1685::AID-ZAAC1685>3.0.CO;2-M

Multiple expression of molecular information: enforced generation of different supramolecular inorganic architectures by processing of the same ligand information through specific coordination algorithms
D. P. Funeriu, J.-M. Lehn, K. M. Fromm, D. Fenske, Chem. Eur. J. 20006(12), 2103-2111. DOI: 10.1002/1521-3765(20000616)6:12<2103::AID-CHEM2103>3.0.CO;2-S

H-bonded polymer structures of different dimensionality: syntheses and crystal structures of [Ca(DME)n(H2O)m]I2·(DME)x (1: n=3, m=3, x=1; 2: n=2, m=4, x=0) and [Ca{CH3(OCH2)3OCH3}(H2O)4]I2
K. M. Fromm, H. Goesmann, G. Bernardinelli,  Polyhedron 200019(15), 1783-1789. DOI: 10.1016/S0277-5387(00)00466-6

On the way to sol-gels: an analysis of the intra- and intermolecular hydrogen bonding in [Ba(OH)I(H2O)4]
K. M. Fromm, H. Goesmann, Acta Cryst. Sect. C 2000, C56(10), 1179-1180. DOI: 10.1107/S0108270100009586

Synthesis and crystal structure of [IBa(OtBu)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium
K. M. Fromm, E. D. Gueneau, H. Goesmann, Chem. Commun. 2000, (22), 2187-2188. DOI: 10.1039/B005638N

1999

Synthesis and crystal structure of Li[{Ca73-OH)8I6(thf)12}2(µ-I)]·3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol–gels
K. M. Fromm, Chem. Comm. 199917, 1659-1660.  DOI: 10.1039/A904560K

1998

Structural evolution from the solid state to the molecule for BaI: synthesis and crystal structures of [BaI22-OH2)2]3/∞, [BaI22-OH2)(OC3H6)]2/∞, [BaI2(thf)3]1/∞, and [BaI2(thf)5] · THF
K. M. Fromm, Angew. Chem. 1998, 109(24), 2876-2878; Angew. Chem. Int. Ed. Engl. 199836(24), 2799-2801.  DOI: 10.1002/anie.199727991

Toposelective and chiroselective self-assembly of [2×2] grid-type inorganic arrays containing different octahedral metallic centers
D. M. Bassani, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl1998, 37(17), 2364-2367.  DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2364::AID-ANIE2364>3.0.CO;2-7

1997

Organometallic tantalum complexes with phosphine, phosphanido and phosphinidene ligands. Syntheses and crystal structures of [Cp′TaCl4[PH2(2, 4, 6-Pri3C6H2)]], [Cp′Ta(μ-PPh2)(PPh2)]2·C7H8 and [Cp′TaCl[μ-P(2, 4, 6-Pri3C6H2)]]2· C7H8(Cp′ =C5H4Me)
G. A. Abdul Hadi, K. M. Fromm, S. Blaurock, S. Jelonek, E. Hey-Hawkins,  Polyhedron 199716(4), 721-731.  DOI: 10.1016/0277-5387(96)00269-0

Reducible nanoscale molecular rods based on diacetylene-linked poly(phenylthio)-substituted benzenes
M. Mayor, J.-M. Lehn, K. M. Fromm, D. Fenske, Angew. Chem. Int. Ed. Engl. 199736(21), 2370-2372. DOI: 10.1002/anie.199723701

1996

Zintl anions as starting compounds for the synthesis of polynuclear transition metal complexes
R. Ahlrichs, D. Fenske, K. M. Fromm, H. Krautscheid, U. Krautscheid, O. Treutler, Chem. Eur. J. 1996, 2(2), 238-244.  DOI: 10.1002/chem.19960020217

1995

Mixed-valence dinuclear molybdenum complexes: synthesis and molecular structure of (Cp°Mo)2(μ-Cl)n(μ-PPh2)3-n (n=1, 0; Cp° = η5-C5Me4Et)
E. Hey-HawkinsK. M. Fromm, Polyhedron 199514(15/16), 2027-2035.  DOI:10.1016/0277-5387(95)00040-Y

Synthesis and molecular structures of molybdenum complexes with phosphido, diphosphanyland diphosphene ligands 
E. Hey-HawkinsK. M. Fromm, Polyhedron 199514(20/21), 2825-2834.  DOI:10.1016/0277-5387(95)00220-M

Synthesis and molecular structures of the molybdenum(II) complexes MoCl2(PMe3)2 and [Mo(μ-PPh2)(PPh2)(PMe3)]2
K. M. Fromm,  M. Plaikner, E. Hey-Hawkins, Z. Naturforsch. 199550(6), 894-898.  DOI: 10.1515/znb-1995-0610

1993

Reaction of cyclopentadienyl substituted molybdenum (V) tetrachlorides with LiPH(2,4,6-But3C6H2) and KPPh2(dioxane)2. Crystal structures of [Cp0Mo(μ-Cl)2]2 and [Cpmath imageMo2(μ-Cl)3(μ-PPh2)] (Cp0 = C5Me4Et)
K. M. Fromm, E. Hey-Hawkins, Z. anorg. allg. Chem. 1993619(2), 261-270.  DOI: 10.1002/zaac.19936190207

1992

Synthesis and crystal structure of meso-(1,2,3-tricyclohexyltriphosphine-1,3-diyl)zirconocene (IV), [cyclic] Cp2Zr(PCy-PCy-PCy) (Cp =  η5-C5H5 ; Cy = C6H11)
K. M. Fromm, G. Baum, E. Hey-Hawkins, Z. anorg. allg. Chem. 1992615, 35-38.  DOI: 10.1002/zaac.19926150907